Highly Efficient and Monodisperse Graphene Oxide Furnished Ru/Pd Nanoparticles for the Dehalogenation of Aryl Halides via Ammonia Borane

Yükleniyor...
Küçük Resim

Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Wiley-V C H Verlag Gmbh

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Highly monodisperse graphene oxide-supported Ru/Pd nanoparticles (RuPd@GO NPs) have been reproducibly and easily synthesized by microwave assisted method. RuPd@GO NPs was performed for dehalogenation of arylhalides in the presence of ammonia borane in a mild condition as novel, highly efficient and exceptional reusable heterogeneous catalyst. The novel materials were characterized by transmission electron microscopy (TEM), the high resolution electron micrograph (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results showed that the prepared catalysts are highly crystalline, monodisperse and colloidally stable. The current one-pot catalytic process was described as a new methodology for dehalogenation of arylhalides which can be assessed as a quite simple, eco-friendly and highly efficient as well as exceptional reusable. All products were provided with one of the highest yield and the shortest time in the presence of novel RuPd@GO NPs due to the the synergistic effect of Ru and Pd. Our synthesis process comes with a facile and eco-friendly option to RuPd@GO NPs, allowing further scrutiny of current catalysts for numerous other chemical reactions.

Açıklama

WOS: 000395396400013

Anahtar Kelimeler

Dehalogenation, RuPd@GO NPs, ammonia borane, graphene oxide, nanoparticles

Kaynak

Chemistryselect

WoS Q Değeri

Q4

Scopus Q Değeri

Q2

Cilt

1

Sayı

5

Künye