Single-Walled Carbon Nanotube Supported PtNi Nanoparticles (PtNi@SWCNT) Catalyzed Oxidation of Benzyl Alcohols to the Benzaldehyde Derivatives in Oxygen Atmosphere

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dc.authoridCellat, Kemal/0000-0001-6750-480X
dc.authoridSEN, FATIH/0000-0001-6843-9026
dc.authorwosidCellat, Kemal/Y-9636-2019
dc.contributor.authorGoksu, Haydar
dc.contributor.authorCellat, Kemal
dc.contributor.authorSen, Fatih
dc.date.accessioned2021-12-01T18:48:42Z
dc.date.available2021-12-01T18:48:42Z
dc.date.issued2020
dc.department[Belirlenecek]en_US
dc.description.abstractThis study reports a developed process which is a general and facile method for the oxidation of benzyl alcohol (BnOH) compounds to the benzaldehyde (BA) derivatives, under mild conditions. The oxidation of BnOH species catalyzed by PtNi@SWCNT in toluene (3ml) at 80 degrees C under a continuous stream of O-2. Single wall carbon nanotube supported PtNi (PtNi@SWCNT) nanoparticles were synthesized using a single-step modified reduction process. The characterization of PtNi@SWCNT nanocatalyst was performed by transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and elemental analysis by ICP-OES. A variety of BnOH compounds were oxidized by the PtNi@SWCNT catalyst and all the expected oxidation products were obtained in high efficiency in 2hours of reaction time. TLC was used to monitoring the reaction progress, and the products were identified by H-1/C-13-NMR analysis.en_US
dc.description.sponsorshipDumlupnar University [2014-05]; Duzce UniversityDuzce University [2018.26.04.880]en_US
dc.description.sponsorshipThe authors would like to thank Dumlupnar University (BAP Project Number: 2014-05) and Duzce University (BAP Project Number: 2018.26.04.880) for their support of this work.en_US
dc.identifier.doi10.1038/s41598-020-66492-x
dc.identifier.issn2045-2322
dc.identifier.issue1en_US
dc.identifier.pmid32541661en_US
dc.identifier.scopus2-s2.0-85086619572en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1038/s41598-020-66492-x
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10590
dc.identifier.volume10en_US
dc.identifier.wosWOS:000544937000007en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherNature Publishing Groupen_US
dc.relation.ispartofScientific Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSelective Aerobic Oxidationen_US
dc.subjectHighly Efficienten_US
dc.subjectGraphene Oxideen_US
dc.subjectNickel Nanoparticlesen_US
dc.subjectAlloy Nanoparticlesen_US
dc.subjectGolden_US
dc.subjectPalladiumen_US
dc.subjectHydrogenationen_US
dc.subjectNanocatalystsen_US
dc.subjectNitroarenesen_US
dc.titleSingle-Walled Carbon Nanotube Supported PtNi Nanoparticles (PtNi@SWCNT) Catalyzed Oxidation of Benzyl Alcohols to the Benzaldehyde Derivatives in Oxygen Atmosphereen_US
dc.typeArticleen_US

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