Single-Walled Carbon Nanotube Supported PtNi Nanoparticles (PtNi@SWCNT) Catalyzed Oxidation of Benzyl Alcohols to the Benzaldehyde Derivatives in Oxygen Atmosphere

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Küçük Resim

Tarih

2020

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Nature Publishing Group

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

This study reports a developed process which is a general and facile method for the oxidation of benzyl alcohol (BnOH) compounds to the benzaldehyde (BA) derivatives, under mild conditions. The oxidation of BnOH species catalyzed by PtNi@SWCNT in toluene (3ml) at 80 degrees C under a continuous stream of O-2. Single wall carbon nanotube supported PtNi (PtNi@SWCNT) nanoparticles were synthesized using a single-step modified reduction process. The characterization of PtNi@SWCNT nanocatalyst was performed by transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and elemental analysis by ICP-OES. A variety of BnOH compounds were oxidized by the PtNi@SWCNT catalyst and all the expected oxidation products were obtained in high efficiency in 2hours of reaction time. TLC was used to monitoring the reaction progress, and the products were identified by H-1/C-13-NMR analysis.

Açıklama

Anahtar Kelimeler

Selective Aerobic Oxidation, Highly Efficient, Graphene Oxide, Nickel Nanoparticles, Alloy Nanoparticles, Gold, Palladium, Hydrogenation, Nanocatalysts, Nitroarenes

Kaynak

Scientific Reports

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

10

Sayı

1

Künye