CoPd alloy nanoparticles catalyzed tandem ammonia borane dehydrogenation and reduction of aromatic nitro, nitrile and carbonyl compounds

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dc.contributor.authorGöksu, Haydar
dc.contributor.authorCan, Hasan
dc.contributor.authorŞendil, Kıvılcım
dc.contributor.authorGültekin, Mehmet Serdar
dc.contributor.authorMetin, Önder
dc.date.accessioned2020-04-30T22:41:46Z
dc.date.available2020-04-30T22:41:46Z
dc.date.issued2014
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionCan, Hasan/0000-0002-5723-2959; Metin, Onder/0000-0003-1622-4992en_US
dc.descriptionWOS: 000346214100020en_US
dc.description.abstractAddressed herein is a general and facile route for the reduction of aromatic nitro, nitrile, and carbonyl compounds to the corresponding primary amines and alcohols, respectively, under ambient conditions. Our reduction approach comprises the tandem AB dehydrogenation and hydrogenation of unsaturated organic groups catalyzed by reduced graphene oxide supported Co30Pd70 alloy nanoparticles (rGO-Co30Pd70) in water/methanol mixture (v/v = 7/3) at room temperature. Monodisperse Co30Pd70 alloy NPs were synthesized by using an organic solution phase protocol involving the co-reduction of cobalt(II) acetylacetonate and palladium(II) acetylacetonate in oleylamine and borane-tert-butylamine mixture at 100 degrees C. The colloidal Co30Pd70 NPs were assembled on reduced graphene oxide (rGO-Co30Pd70) before their use as catalysts in the tandem reactions. A variety of aromatic nitro, nitriles, and carbonyl compounds were tested by the rGO-Co30Pd70 catalyzed tandem reaction and all the corresponding primary amines or alcohols were obtained by the yields reaching up to 99% within reaction times of 5-15 min. (C) 2014 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z276]; Turkish Academy of Science Young Scientist program (TUBA-GEBIP)Turkish Academy of Sciencesen_US
dc.description.sponsorshipThe financial support by the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 113Z276) and partial support by Turkish Academy of Science Young Scientist program (TUBA-GEBIP) is highly acknowledged.en_US
dc.identifier.doi10.1016/j.apcata.2014.09.043en_US
dc.identifier.endpage182en_US
dc.identifier.issn0926-860X
dc.identifier.issn1873-3875
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage176en_US
dc.identifier.urihttps://doi.org/10.1016/j.apcata.2014.09.043
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3244
dc.identifier.volume488en_US
dc.identifier.wosWOS:000346214100020en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofApplied Catalysis A-Generalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCoPden_US
dc.subjectAlloy nanoparticlesen_US
dc.subjectAmmonia-boraneen_US
dc.subjectDehydrogenationen_US
dc.subjectTandem hydrogenationen_US
dc.titleCoPd alloy nanoparticles catalyzed tandem ammonia borane dehydrogenation and reduction of aromatic nitro, nitrile and carbonyl compoundsen_US
dc.typeArticleen_US

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