Superior Monodisperse CNT-Supported CoPd (CoPd@CNT) Nanoparticles for Selective Reduction of Nitro Compounds to Primary Amines with NaBH4 in Aqueous Medium

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dc.contributor.authorGöksu, Haydar
dc.contributor.authorÇelik, Betül
dc.contributor.authorYıldız, Yunus
dc.contributor.authorŞen, Fatih
dc.contributor.authorKılbaş, Benan
dc.date.accessioned2020-04-30T23:32:19Z
dc.date.available2020-04-30T23:32:19Z
dc.date.issued2016
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionWOS: 000395417800040en_US
dc.description.abstractSuperior carbon nanotube furnished CoPd (CoPd@CNT) nanoparticles (NPs) were reproducibly and easily produced by sonochemical double solvent reduction method in a mild condition and the size of the CoPd NPs was found as 3.63 nm. The prepared novel catalyst were characterized by transmission electron microscopy (TEM), the high resolution electron micrograph (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The sum of their results showed the formation of highly crystalline, monodisperse and colloidally stable CoPd@CNT. The catalytic performance of these novel NPs were investigated for the first time for highly selective reduction to -NO2 unlike -CN groups, in which they were found to be exceptional reusable, isolable, stable and highly efficient heterogeneous catalyst. All prepared products were obtained with perfect yield by using CoPd@CNT as a heterogeneous catalyst and NaBH4 as a hydrogen source. Our synthesis process provides a facile and eco-friendly route to CoPd@CNT, allowing further investigation of current catalysts for many other chemical reactions.en_US
dc.description.sponsorshipDuzce UniversityDuzce University [2013.05.03.188, 2015.26.04.371]; Dumlupinar University Research FundDumlupinar University [2014-05, 2015-35, 2015-50]; Science Academy; FABEDen_US
dc.description.sponsorshipThis research was supported by Duzce University (grant no. 2013.05.03.188 and 2015.26.04.371) and Dumlupinar University Research Fund (2014-05, 2015-35 and 2015-50). The partial supports from Science Academy and FABED are highly acknowledged.en_US
dc.identifier.doi10.1002/slct.201600509en_US
dc.identifier.endpage2372en_US
dc.identifier.issn2365-6549
dc.identifier.issue10en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2366en_US
dc.identifier.urihttps://doi.org/10.1002/slct.201600509
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4684
dc.identifier.volume1en_US
dc.identifier.wosWOS:000395417800040en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTandem Hydrogenationen_US
dc.subjectCoPd@CNT NPsen_US
dc.subjectsodium borohydrideen_US
dc.subjectcarbon nanotubeen_US
dc.subjectnanoparticlesen_US
dc.titleSuperior Monodisperse CNT-Supported CoPd (CoPd@CNT) Nanoparticles for Selective Reduction of Nitro Compounds to Primary Amines with NaBH4 in Aqueous Mediumen_US
dc.typeArticleen_US

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