High temperature bromination Part XXIII: Bromination of octahydro-1H-indene and octahydro-1H-4,7-methanoindene

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dc.contributor.authorÖzer, Melek Şermin
dc.contributor.authorKılbaş, Benan
dc.contributor.authorBalcı, Metin
dc.date.accessioned2020-05-01T12:10:22Z
dc.date.available2020-05-01T12:10:22Z
dc.date.issued2013
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000330029300030en_US
dc.description.abstractThermal and photobromination of octahydro-1H-indene and octahydro-1H-4,7-methanoindene were investigated. Three isomeric tetrabromides (1,3,4,7-tetrabromo-2,3,4,5,6,7-hexahydro-1-H-indene) were formed along with a smaller amount of tribromoindane and a pentabromide by thermal bromination of octahydro-1H-indene. The thermodynamically most stable isomers were formed. Morover, thermal and photochemical bromination of octahydro-1H-4,7-methanoindene furnished bromides resulting regiospecifically from the allylic bromination of the five-membered ring. Furthermore, the double bond formed as the intermediate functional group was also brominated due to its pyramidalization. The mechanism proposed for the formation of product distribution was discussed.en_US
dc.description.sponsorshipTUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [108-M168]; Department of Chemistry at Middle East Technical University; TUBA (Turkish Academy of Sciences)Turkish Academy of Sciencesen_US
dc.description.sponsorshipThe authors are indebted to TUBITAK (Scientific and Technological Research Council of Turkey), (Grant 108-M168), the Department of Chemistry at Middle East Technical University and TUBA (Turkish Academy of Sciences) for financial support of this work.en_US
dc.identifier.doi10.3998/ark.5550190.p008.195en_US
dc.identifier.endpage404en_US
dc.identifier.issn1551-7004
dc.identifier.issn1551-7012
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage388en_US
dc.identifier.urihttps://doi.org/10.3998/ark.5550190.p008.195
dc.identifier.urihttps://hdl.handle.net/20.500.12684/6163
dc.identifier.wosWOS:000330029300030en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherArkat Usa Incen_US
dc.relation.ispartofArkivocen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBrominationen_US
dc.subjecthigh temperature brominationen_US
dc.subjecthydrocarbonsen_US
dc.subjectsubstitutionen_US
dc.titleHigh temperature bromination Part XXIII: Bromination of octahydro-1H-indene and octahydro-1H-4,7-methanoindeneen_US
dc.typeArticleen_US

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