Synthesis of benzylidenemalononitrile by Knoevenagel condensation through monodisperse carbon nanotube-based NiCu nanohybrids

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dc.authoridBurhan, Hakan/0000-0002-2293-7369
dc.authoridSEN, FATIH/0000-0001-6843-9026
dc.authoridSEN, FATIH/0000-0001-9929-9556
dc.authorwosidBurhan, Hakan/AAE-6124-2020
dc.contributor.authorZengin, Nursefa
dc.contributor.authorBurhan, Hakan
dc.contributor.authorSavk, Aysun
dc.contributor.authorGoksu, Haydar
dc.contributor.authorSen, Fatih
dc.date.accessioned2021-12-01T18:48:16Z
dc.date.available2021-12-01T18:48:16Z
dc.date.issued2020
dc.department[Belirlenecek]en_US
dc.description.abstractMonodisperse nickel/copper nanohybrids (NiCu@MWCNT) based on multi-walled carbon nanotubes (MWCNT) were prepared for the Knoevenagel condensation of aryl and aliphatic aldehydes. The synthesis of these nanohybrids was carried out by the ultrasonic hydroxide assisted reduction method. NiCu@MWCNT nanohybrids were characterized by analytical techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), and Raman spectroscopy. According to characterization results, NiCu@MWCNT showed that these nanohybrids form highly uniform, crystalline, monodisperse, colloidally stable NiCu@MWCNT nanohybrids were successfully synthesized. Thereafter, a model reaction was carried out to obtain benzylidenemalononitrile derivatives using NiCu@MWCNT as a catalyst, and showed high catalytic performance under mild conditions over 10-180 min.en_US
dc.description.sponsorshipDumlupinar UniversityDumlupinar University [2014-05, 2015-35, 2015-50]; Duzce UniversityDuzce University [2015.26.04.371]en_US
dc.description.sponsorshipThe authors would like to thank Dumlupinar University (2014-05, 2015-35, and 2015-50) and Duzce University (grant no. 2015.26.04.371) for funding.en_US
dc.identifier.doi10.1038/s41598-020-69764-8
dc.identifier.issn2045-2322
dc.identifier.issue1en_US
dc.identifier.pmid32728177en_US
dc.identifier.scopus2-s2.0-85088705103en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1038/s41598-020-69764-8
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10496
dc.identifier.volume10en_US
dc.identifier.wosWOS:000556388300012en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherNature Publishing Groupen_US
dc.relation.ispartofScientific Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectRecyclable Heterogeneous Catalysten_US
dc.subjectMetal-Organic Frameworksen_US
dc.subjectHighly Efficienten_US
dc.subjectGraphene Oxideen_US
dc.subjectAryl Halidesen_US
dc.subjectAt-Goen_US
dc.subjectNanoparticlesen_US
dc.subjectAldehydesen_US
dc.subjectDehalogenationen_US
dc.subjectMalononitrileen_US
dc.titleSynthesis of benzylidenemalononitrile by Knoevenagel condensation through monodisperse carbon nanotube-based NiCu nanohybridsen_US
dc.typeArticleen_US

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