One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(epsilon-caprolactone) Graft Copolymers

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dc.contributor.authorAllı, Abdulkadir
dc.contributor.authorAllı, Sema
dc.contributor.authorBecer, C. Remzi
dc.contributor.authorHazer, Baki
dc.date.accessioned2020-04-30T23:20:13Z
dc.date.available2020-04-30T23:20:13Z
dc.date.issued2014
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionBecer, C. Remzi/0000-0003-0968-6662;en_US
dc.descriptionWOS: 000335153500016en_US
dc.description.abstractOne-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.en_US
dc.description.sponsorshipTurkish Scientific Research CouncilTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [110T884, 211T016]; Duzce University Research FundDuzce University [2011.05.HD.026, 2011.05.03.068, 2011.05.HD.052]; Bulent Ecevit University Research FundBulent Ecevit University [2012-10-03-03]en_US
dc.description.sponsorshipThis work was supported financially by the Turkish Scientific Research Council (Grants Numbers: 110T884, 211T016), the Duzce University Research Fund (Grant Number: 2011.05.HD.026, 2011.05.03.068, 2011.05.HD.052) the Bulent Ecevit University Research Fund (Grant Number: 2012-10-03-03).en_US
dc.identifier.doi10.1007/s11746-014-2418-1en_US
dc.identifier.endpage858en_US
dc.identifier.issn0003-021X
dc.identifier.issn1558-9331
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage849en_US
dc.identifier.urihttps://doi.org/10.1007/s11746-014-2418-1
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3959
dc.identifier.volume91en_US
dc.identifier.wosWOS:000335153500016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of The American Oil Chemists Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAutoxidationen_US
dc.subjectOne-pot polymerizationen_US
dc.subjectepsilon-Caprolactoneen_US
dc.subjectPolymeric linoleic acid peroxidesen_US
dc.titleOne-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(epsilon-caprolactone) Graft Copolymersen_US
dc.typeArticleen_US

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