One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(epsilon-caprolactone) Graft Copolymers
Yükleniyor...
Dosyalar
Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
One-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.
Açıklama
Becer, C. Remzi/0000-0003-0968-6662;
WOS: 000335153500016
WOS: 000335153500016
Anahtar Kelimeler
Autoxidation, One-pot polymerization, epsilon-Caprolactone, Polymeric linoleic acid peroxides
Kaynak
Journal Of The American Oil Chemists Society
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
91
Sayı
5
