Eco-friendly hydrogenation of aromatic aldehyde compounds by tandem dehydrogenation of dimethylamine-borane in the presence of a reduced graphene oxide furnished platinum nanocatalyst

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dc.contributor.authorGöksu, Haydar
dc.contributor.authorYıldız, Yunus
dc.contributor.authorÇelik, Betül
dc.contributor.authorYazıcı, Melike
dc.contributor.authorKılbaş, Benan
dc.contributor.authorŞen, Fatih
dc.date.accessioned2020-05-01T09:11:33Z
dc.date.available2020-05-01T09:11:33Z
dc.date.issued2016
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionWOS: 000373608400033en_US
dc.description.abstractIn this study, highly monodisperse platinum nanoparticles supported on reduced graphene oxide in the presence of tripentylamine (TPA) (Pt(0)/TPA@rGO NPs) are used as a stable, isolable, bottleable, long-lived, highly efficient and exceptionally reusable heterogeneous catalyst for eco-friendly hydrogenation of various aromatic aldehyde compounds with unprecendented catalytic performance. Pt(0)/TPA@rGO NPs have been used for the first time for these types of synthesis reactions and these NPs were characterized by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). Herein, the catalyst has been used for tandem dehydrogenation of dimethylamine-borane (DMAB) and hydrogenation of aromatic aldehyde compounds in aqueous methanol at room temperature in reaction times ranging from 1.0 to 25 min with yields reaching up to 95%. The presented catalytic methodology is highly efficient as well as having exceptional reusability performance. This process can be assessed as an eco-friendly method with both a reusable reduced GO-supported platinum nanocatalyst and a hydrogen source (DMAB).en_US
dc.description.sponsorshipDuzce UniversityDuzce University [2015.05.03.333, 2014.05.03.264]; Dumlupinar University Research Funding AgencyDumlupinar University [2014-05, 2015-50]; Science Academyen_US
dc.description.sponsorshipThis research was supported by Duzce University (grant no. 2015.05.03.333 and 2014.05.03.264) and Dumlupinar University Research Funding Agency (2014-05 and 2015-50). Partial support from the Science Academy is gratefully acknowledged.en_US
dc.identifier.doi10.1039/c5cy01462jen_US
dc.identifier.endpage2324en_US
dc.identifier.issn2044-4753
dc.identifier.issn2044-4761
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2318en_US
dc.identifier.urihttps://doi.org/10.1039/c5cy01462j
dc.identifier.urihttps://hdl.handle.net/20.500.12684/5658
dc.identifier.volume6en_US
dc.identifier.wosWOS:000373608400033en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofCatalysis Science & Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleEco-friendly hydrogenation of aromatic aldehyde compounds by tandem dehydrogenation of dimethylamine-borane in the presence of a reduced graphene oxide furnished platinum nanocatalysten_US
dc.typeArticleen_US

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