Synthesis and Characterization of Nearly Monodisperse Pt Nanoparticles for C-1 to C-3 Alcohol Oxidation and Dehydrogenation of Dimethylamine-borane (DMAB)

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dc.contributor.authorErken, Esma
dc.contributor.authorYıldız, Yunus
dc.contributor.authorKılbaş, Benan
dc.contributor.authorŞen, Fatih
dc.date.accessioned2020-04-30T23:32:25Z
dc.date.available2020-04-30T23:32:25Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000386123900075en_US
dc.descriptionPubMed: 27427655en_US
dc.description.abstractHighly efficient nearly monodisperse Pt NPs catalyze C1 to C3 alcohol oxidation with very high electrochemical activities and provides one of the highest catalytic activities (TOF = 21.50 h(-1)) in the dehydrogenation of DMAB at room temperature. The exceptional stability towards agglomeration, leaching and CO poisoning for the prepared catalyst allow these particles to be recycled and reused in the catalysis of both DMAB dehydrogenation and C1 to C3 alcohol oxidation. After four subsequent reaction and recovery cycles, catalyst retained >= 80% activity towards the complete dehydrogenation of DMAB. The prepared catalyst structures were determined by the X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), atomic force microscopy (AFM) and transmission electron microscopy (TEM) respectively.en_US
dc.description.sponsorshipDumlupinar UniversityDumlupinar University [DPU-2014-5]; Duzce UniversityDuzce University [DUBAP-2014.05.03.243]en_US
dc.description.sponsorshipThe authors would like to thank Dumlupinar University (DPU-2014-5) and Duzce University (DUBAP-2014.05.03.243) for the financial support.en_US
dc.identifier.doi10.1166/jnn.2016.11683en_US
dc.identifier.endpage5950en_US
dc.identifier.issn1533-4880
dc.identifier.issn1533-4899
dc.identifier.issue6en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage5944en_US
dc.identifier.urihttps://doi.org/10.1166/jnn.2016.11683
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4715
dc.identifier.volume16en_US
dc.identifier.wosWOS:000386123900075en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Scientific Publishersen_US
dc.relation.ispartofJournal Of Nanoscience And Nanotechnologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDirect Alcohol Fuel Cells (DAFCs)en_US
dc.subjectAtomic Force Microscopy (AFM)en_US
dc.subjectTransmission Electron Microscopy (TEM)en_US
dc.subjectPlatinum NPsen_US
dc.subjectX-ray Photoelectron Spectroscopyen_US
dc.titleSynthesis and Characterization of Nearly Monodisperse Pt Nanoparticles for C-1 to C-3 Alcohol Oxidation and Dehydrogenation of Dimethylamine-borane (DMAB)en_US
dc.typeArticleen_US

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