Multicomponent Assembly of Macrocycles and Polymers by Coordination of Pyridyl Ligands to 1,4-Bis(benzodioxaborole)benzene

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dc.contributor.authorİçli, Burçak
dc.contributor.authorSolari, Euro
dc.contributor.authorKılbaş, Benan
dc.contributor.authorScopelliti, Rosario
dc.contributor.authorSeverin, Kay
dc.date.accessioned2020-04-30T23:19:23Z
dc.date.available2020-04-30T23:19:23Z
dc.date.issued2012
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000310800200038en_US
dc.descriptionPubMed: 23019077en_US
dc.description.abstractMulticomponent reactions between 1,4-benzenediboronic acid, catechol, and different pyridyl ligands are reported. The condensation of 1,4-benzenediboronic acid with catechol gives 1,4-bis(benzodioxaborole)benzene. Upon crystallization, the ester aggregates with the N-donor ligands through dative B-N bonds. Depending on the nature of the pyridyl ligand, molecularly defined macrocycles or polymeric structures are obtained. 1D polymers are formed with 4,4-bipyridine and 1,2-di(4-pyridyl)ethylene, whereas a 2D network is obtained with the tetradentate ligand tetra(4-pyridylphenyl)ethylene. These results highlight the utility of dative B-N bonds in structural supramolecular chemistry and crystal engineering.en_US
dc.description.sponsorshipSwiss National Science FoundationSwiss National Science Foundation (SNSF); EPFL; TUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThe work was supported by the Swiss National Science Foundation, the EPFL, and by the TUBITAK (Scientific and Technological Research Council of Turkey).en_US
dc.identifier.doi10.1002/chem.201202313en_US
dc.identifier.endpage14874en_US
dc.identifier.issn0947-6539
dc.identifier.issue46en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage14867en_US
dc.identifier.urihttps://doi.org/10.1002/chem.201202313
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3742
dc.identifier.volume18en_US
dc.identifier.wosWOS:000310800200038en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistry-A European Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectboronic acidsen_US
dc.subjectdative bondsen_US
dc.subjectmacrocyclesen_US
dc.subjectpolymersen_US
dc.subjectsupramolecular chemistryen_US
dc.titleMulticomponent Assembly of Macrocycles and Polymers by Coordination of Pyridyl Ligands to 1,4-Bis(benzodioxaborole)benzeneen_US
dc.typeArticleen_US

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