Handy and highly efficient oxidation of benzylic alcohols to the benzaldehyde derivatives using heterogeneous Pd/AlO(OH) nanoparticles in solvent-free conditions

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dc.contributor.authorGöksu, Haydar
dc.contributor.authorŞen, Fatih
dc.date.accessioned2020-04-30T13:32:32Z
dc.date.available2020-04-30T13:32:32Z
dc.date.issued2020
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionPubMed ID: 32235857en_US
dc.description.abstractThe selective oxidation of benzylic alcohols was performed by using commercially available aluminum oxy-hydroxide-supported palladium (Pd/AlO(OH)) nanoparticles (0.5 wt.% Pd, about 3 nm size) under mild conditions. The oxidation method comprises the oxidation of benzyl alcohols catalyzed by aluminum oxy-hydroxide-supported palladium under ultrasonic and solvent-free conditions and a continuous stream of O2. The characterization of aluminum oxy-hydroxide-supported palladium nanocatalyst was conducted by several advanced analytical techniques including scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and elemental analysis by ICP-OES. The oxidation of a variety of benzyl alcohol compounds were tested by the aluminum oxy-hydroxide-supported palladium nanoparticles, and all expected oxidation products were obtained by the high conversion yields within 3 hours. The reaction progress was monitored by TLC (Thin-layer chromatography), and the yields of the products were determined by 1H-NMR and 13C NMR analysis. © 2020, The Author(s).en_US
dc.description.sponsorship2015.26.04.371, 2019.26.04.979en_US
dc.description.sponsorshipThis study was supported by Duzce University Research Fund (grant no. 2015.26.04.371 and 2019.26.04.979).en_US
dc.identifier.doi10.1038/s41598-020-62695-4en_US
dc.identifier.issn2045-2322
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://dx.doi.org/10.1038/s41598-020-62695-4
dc.identifier.urihttps://hdl.handle.net/20.500.12684/336
dc.identifier.volume10en_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherNature Researchen_US
dc.relation.ispartofScientific Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleHandy and highly efficient oxidation of benzylic alcohols to the benzaldehyde derivatives using heterogeneous Pd/AlO(OH) nanoparticles in solvent-free conditionsen_US
dc.typeArticleen_US

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