Simultaneous microextraction of Brilliant Blue FCF, Malachite Green, and Rhodamine B in children's play materials: Assessment of greenness approach

Küçük Resim Yok

Tarih

2025

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Pergamon-Elsevier Science Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The types, quantities, and permissible limits of dyestuffs used in the toy industry are susceptible since the relevant audience is children. For this reason, the dyestuffs used in children's play materials are one of the crucial issues to be emphasized. Rhodamine B, Brilliant Blue FCF, and Malachite Green are some of the most commonly used dyestuffs, and they are also included in our study. In addition to making play materials fun for children, it is vital to determine the amount of the dye in the play material to know the damage it will cause. For this purpose, an ultrasonically assisted, rapid, and highly sensitive green deep eutectic solvent-based microextraction method was developed to detect three synthetic dyes in different children's play materials. Extraction recoveries were between 92.8 and 103.2% under optimum conditions. The method was promising when the results obtained were compared with other studies. When additional recovery studies were carried out on different children's play materials, Rhodamine B in pink-coloured playdough and finger paint, Brilliant Blue FCF in blue-coloured playdough, finger paint, and watercolour paint, and Malachite green dyestuffs in finger paint and crayon were detected. In addition, this study is noteworthy as it is the first study in which simultaneous determination of three dyestuffs by high-performance liquid chromatography method was carried out.

Açıklama

Anahtar Kelimeler

Deep eutectic solvents, Greenness approach, Microextraction, Rhodamine B, Brilliant Blue FCF, Malachite green

Kaynak

Spectrochimica Acta Part A-Molecularand Biomolecular Spectroscopy

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

336

Sayı

Künye