A Novel Hydrogenation of Nitroarene Compounds with Multi Wall Carbon Nanotube Supported Palladium/Copper Nanoparticles (PdCu@MWCNT NPs) in Aqueous Medium

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dc.authoridCellat, Kemal/0000-0001-6750-480X
dc.authoridBurhan, Hakan/0000-0002-2293-7369
dc.authoridSEN, FATIH/0000-0001-9929-9556
dc.authoridSEN, FATIH/0000-0001-6843-9026
dc.authorwosidCellat, Kemal/Y-9636-2019
dc.authorwosidBurhan, Hakan/AAE-6124-2020
dc.contributor.authorGoksu, Haydar
dc.contributor.authorZengin, Nursefa
dc.contributor.authorBurhan, Hakan
dc.contributor.authorCellat, Kemal
dc.contributor.authorSen, Fatih
dc.date.accessioned2021-12-01T18:48:45Z
dc.date.available2021-12-01T18:48:45Z
dc.date.issued2020
dc.department[Belirlenecek]en_US
dc.description.abstractA novel nanocatalyst, multi-wall carbon nanotube supported palladium/copper (PdCu@MWCNT) nanoparticles, was synthesized for the reduction of nitroarene compounds. Characterization of the nanocatalyst was achieved by XRD, XPS, TEM, and Raman spectroscopy analysis. In this study, the hydrogenation of nitroarenes to primary amine compounds was achieved in aqueous medium at room temperature. The aniline derivatives were synthesized with high yields at mild conditions via novel PdCu@MWCNT nanocatalyst. The conversion of nitroarenes to amine derivatives was accomplished at 99% efficiency. In addition to its high activity, the PdCu@MWCNT catalyst was determined to be stable and reusable after the 3rd consecutive use for the reaction and provided 99% conversion of various compounds in the reduction reaction.en_US
dc.description.sponsorshipKaynasli Vocational College at Duzce UniversityDuzce University; TUBA (Turkish Academy of Sciences)Turkish Academy of Sciences; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [BIDEB 2218]en_US
dc.description.sponsorshipThe authors would like to thank Kaynasli Vocational College at Duzce University and TUBA (Turkish Academy of Sciences) for their support of this work. One of the authors, K.C. would like to thank Scientific and Technological Research Council of Turkey (TUBITAK) - BIDEB 2218, for the fellowship.en_US
dc.identifier.doi10.1038/s41598-020-64988-0
dc.identifier.issn2045-2322
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85084787936en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1038/s41598-020-64988-0
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10599
dc.identifier.volume10en_US
dc.identifier.wosWOS:000550077500001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherNature Publishing Groupen_US
dc.relation.ispartofScientific Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCupd Alloy Nanoparticlesen_US
dc.subjectReduced Graphene Oxideen_US
dc.subjectSelective Hydrogenationen_US
dc.subjectAromatic Nitroen_US
dc.subjectCatalystsen_US
dc.subjectReductionen_US
dc.subjectEfficienten_US
dc.subjectNanocrystalsen_US
dc.subjectOxidationen_US
dc.subjectPlatinumen_US
dc.titleA Novel Hydrogenation of Nitroarene Compounds with Multi Wall Carbon Nanotube Supported Palladium/Copper Nanoparticles (PdCu@MWCNT NPs) in Aqueous Mediumen_US
dc.typeArticleen_US

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