Novel Poly(linolenic acid) Graft Copolymers: Synthesis, Characterization and Electrical Properties

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dc.contributor.authorAllı, Abdulkadir
dc.contributor.authorArı, Yurdagül
dc.contributor.authorGökçen, Muharrem
dc.date.accessioned2020-04-30T23:19:44Z
dc.date.available2020-04-30T23:19:44Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionGokcen, Muharrem/0000-0001-9063-3028en_US
dc.descriptionWOS: 000378904400003en_US
dc.description.abstractA poly(linolenic acid)-g-poly(tert-butyl acrylate) graft copolymer was synthesized from polymeric linolenic acid peroxide possessing peroxide groups in the main chain by free radical polymerization of tert-butyl acrylate. Graft copolymers having structures of poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate) were synthesized from polymeric linolenic acid, possessing peroxide groups on the main chain by the combination of free radical polymerization of tert-butyl acrylate and ring-opening polymerization of epsilon-caprolactone in one-pot. The obtained graft copolymers were characterized by proton nuclear magnetic resonance, gel permeation chromatography, thermal gravimetric analysis, differential scanning calorimetry, and scanning electron microscopy techniques. Furthermore, Au/n-Si diodes were fabricated with and without poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate)-4 to form a new interfacial polymeric layer for the purpose of investigating this polymer's conformity in electronic applications. Some main electrical characteristics of these diodes were investigated using experimental current-voltage measurements in the dark and at room temperature.en_US
dc.description.sponsorshipTurkish Scientific Research CouncilTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [110T884]; Duzce University Research FundDuzce University [2014.05.03.234, 2014.05.03.248, 2014.05.02.260, 2015.05.03.343, 2015.05.02.358]en_US
dc.description.sponsorshipThis work was supported financially by the Turkish Scientific Research Council (Grants Number: 110T884), the Duzce University Research Fund (Grant Numbers: 2014.05.03.234, 2014.05.03.248, 2014.05.02.260, 2015.05.03.343, 2015.05.02.358)en_US
dc.identifier.doi10.1007/s11746-016-2834-5en_US
dc.identifier.endpage904en_US
dc.identifier.issn0003-021X
dc.identifier.issn1558-9331
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage895en_US
dc.identifier.urihttps://doi.org/10.1007/s11746-016-2834-5
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3838
dc.identifier.volume93en_US
dc.identifier.wosWOS:000378904400003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of The American Oil Chemists Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAutoxidationen_US
dc.subjectOne-pot polymerizationen_US
dc.subjectLinolenic aciden_US
dc.subjecttert-Butyl acrylateen_US
dc.subjectepsilon-Caprolactoneen_US
dc.subjectElectrical propertiesen_US
dc.titleNovel Poly(linolenic acid) Graft Copolymers: Synthesis, Characterization and Electrical Propertiesen_US
dc.typeArticleen_US

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