Novel Poly(linolenic acid) Graft Copolymers: Synthesis, Characterization and Electrical Properties
Yükleniyor...
Dosyalar
Tarih
2016
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A poly(linolenic acid)-g-poly(tert-butyl acrylate) graft copolymer was synthesized from polymeric linolenic acid peroxide possessing peroxide groups in the main chain by free radical polymerization of tert-butyl acrylate. Graft copolymers having structures of poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate) were synthesized from polymeric linolenic acid, possessing peroxide groups on the main chain by the combination of free radical polymerization of tert-butyl acrylate and ring-opening polymerization of epsilon-caprolactone in one-pot. The obtained graft copolymers were characterized by proton nuclear magnetic resonance, gel permeation chromatography, thermal gravimetric analysis, differential scanning calorimetry, and scanning electron microscopy techniques. Furthermore, Au/n-Si diodes were fabricated with and without poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate)-4 to form a new interfacial polymeric layer for the purpose of investigating this polymer's conformity in electronic applications. Some main electrical characteristics of these diodes were investigated using experimental current-voltage measurements in the dark and at room temperature.
Açıklama
Gokcen, Muharrem/0000-0001-9063-3028
WOS: 000378904400003
WOS: 000378904400003
Anahtar Kelimeler
Autoxidation, One-pot polymerization, Linolenic acid, tert-Butyl acrylate, epsilon-Caprolactone, Electrical properties
Kaynak
Journal Of The American Oil Chemists Society
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
93
Sayı
7
