Synthesis, characterization and electrochemical behavior of some Ni(II), Cu(II), Co(II) and Cd(II) complexes of ONS type tridentate Schiff base ligand

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dc.contributor.authorDurmuş, Sefa
dc.contributor.authorAtahan, Alparslan
dc.contributor.authorZengin, Mustafa
dc.date.accessioned2020-04-30T23:32:29Z
dc.date.available2020-04-30T23:32:29Z
dc.date.issued2011
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptiondurmus, sefa/0000-0001-6974-513Xen_US
dc.descriptionWOS: 000297450400001en_US
dc.descriptionPubMed: 21982158en_US
dc.description.abstractTridentate Schiff base (H2L) ligand was synthesized via condensation of o-hydroxybenzaldehyde and 2-aminothiophenol. The metal complexes were prepared from reaction of the ligand with corresponding metal salts presence of substituted pyridine in two different solvents (MeOH or MeCN). The ligand and metal complexes were then characterized by using FTIR, TGA, H-1 NMR and C-13 NMR spectroscopies. The FTIR spectra showed that H2L was coordinated to the metal ions in tridentate manner with ONS donor sites of the azomethine N, deprotonated phenolic-OH and phenolic-SH. Furthermore, substituted pyridine was coordinated to the central metal atoms. The thermal behavior of the complexes was investigated by using TGA method and dissociations indicated that substituted pyridine and ligand were leaved from coordination. This coordination of the metal complexes was correlated by H-1 NMR and C-13 NMR. Finally, electrochemical behavior of the ligand and a Ni(II) complex were investigated. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipDuzce UniversityDuzce University [2010.05.03.053]en_US
dc.description.sponsorshipThe authors wish to thank Duzce University Scientific Research Fund (Project No: 2010.05.03.053) for their support. We are grateful to Ankara University and Sakarya University Department of Chemistry for spectroscopic measurements.en_US
dc.identifier.doi10.1016/j.saa.2011.07.034en_US
dc.identifier.endpage5en_US
dc.identifier.issn1386-1425
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2011.07.034
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4731
dc.identifier.volume84en_US
dc.identifier.wosWOS:000297450400001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofSpectrochimica Acta Part A-Molecular And Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThio Schiff baseen_US
dc.subjectComplexen_US
dc.subjectTridentate Schiff baseen_US
dc.subjectThermal analysisen_US
dc.subjectElectrochemical behavioren_US
dc.titleSynthesis, characterization and electrochemical behavior of some Ni(II), Cu(II), Co(II) and Cd(II) complexes of ONS type tridentate Schiff base liganden_US
dc.typeArticleen_US

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