Peripherally substituted soluble nickel phthalocyanines: Synthesis, characterization, aggregation behavior and antioxidant properties
Yükleniyor...
Dosyalar
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
World Sci Publ Co Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Tetra-zwitterionic-substituted nickel(II) phthalocyanine derivatives were newly synthesized starting from nonionic 2(3),9(10),16(17),23(24)-tetrakis-[2-(N-((3-dimethylamino)propyl) carbamate)oxyethyl)phthalocyaninato nickel (II). The novel compounds have been characterized by a combination of UV-vis, FT-IR and mass spectroscopies and elemental analysis. The critical micelle concentrations of the prepared compounds were measured, and the antioxidant activities were analyzed with radical scavenging ability of 1,1-dipheny1-2-picrylhydrazyl (DPPH) and with 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS). The zwitterionic molecules showed aggregated spectra in the UV-vis region, and they might be good surfactant candidates for the detergent industry with their appropriate critical micelle concentration (CMC) properties in water. The compounds exhibited ABTS radical scavenging activity and thus they have antioxidant activity.
Açıklama
WOS: 000508130500028
Anahtar Kelimeler
soluble phthalocyanines, zwitterionic substituted phthalocyanines, antioxidant properties, ABTS, critical micelle concentration
Kaynak
Journal Of Porphyrins And Phthalocyanines
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
23
Sayı
11.Dec