Peripherally substituted soluble nickel phthalocyanines: Synthesis, characterization, aggregation behavior and antioxidant properties

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Küçük Resim

Tarih

2019

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

World Sci Publ Co Inc

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Tetra-zwitterionic-substituted nickel(II) phthalocyanine derivatives were newly synthesized starting from nonionic 2(3),9(10),16(17),23(24)-tetrakis-[2-(N-((3-dimethylamino)propyl) carbamate)oxyethyl)phthalocyaninato nickel (II). The novel compounds have been characterized by a combination of UV-vis, FT-IR and mass spectroscopies and elemental analysis. The critical micelle concentrations of the prepared compounds were measured, and the antioxidant activities were analyzed with radical scavenging ability of 1,1-dipheny1-2-picrylhydrazyl (DPPH) and with 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS). The zwitterionic molecules showed aggregated spectra in the UV-vis region, and they might be good surfactant candidates for the detergent industry with their appropriate critical micelle concentration (CMC) properties in water. The compounds exhibited ABTS radical scavenging activity and thus they have antioxidant activity.

Açıklama

WOS: 000508130500028

Anahtar Kelimeler

soluble phthalocyanines, zwitterionic substituted phthalocyanines, antioxidant properties, ABTS, critical micelle concentration

Kaynak

Journal Of Porphyrins And Phthalocyanines

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

23

Sayı

11.Dec

Künye