One-pot synthesis of 1,2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters

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dc.contributor.authorGöksu, Haydar
dc.contributor.authorDalmızrak, Diğdem
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authorGültekin, Mehmet Serdar
dc.contributor.authorÖzkar, Saim
dc.contributor.authorMetin, Önder
dc.date.accessioned2020-04-30T23:20:12Z
dc.date.available2020-04-30T23:20:12Z
dc.date.issued2013
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionMetin, Onder/0000-0003-1622-4992; Akbayrak, Serdar/0000-0003-3858-2985en_US
dc.descriptionWOS: 000324789600018en_US
dc.description.abstractA facile, efficient and eco-friendly method for the one-pot synthesis of 1,2/3-triols from the allylic hydroperoxides were developed by using zeolite-confined osmium(0) nanoclusters as reusable catalyst and without using any co-oxidant (H2O2, (BuOOH)-Bu-t, NMO, etc.) in water/acetone (v/v = 1/4) mixture at room temperature. In this method, the oxygen atom of the allylic hydroperoxide group was transferred to the double bond of the same molecule via zeolite-confined osmium(0) nanoclusters. The method has been successfully applied to various allylic hydroperoxides and the corresponding 1,2/3-triols were obtained in high chemical yield. Moreover, a plausible mechanism was proposed for the catalytic oxidation of allylic hydroperoxide to the respective 1,2/3-triols in the presence of zeolite-Os-0 catalyst gathering all the results collected by testing a variety of allylic hydroperoxides in the presence of zeolite-Os-0 catalyst. (c) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [109T815]; Ataturk University Scientific Research Project CouncilAtaturk University [2010/32, 2011/93]; Turkish Academy of SciencesTurkish Academy of Sciencesen_US
dc.description.sponsorshipPartially support by TUBITAK (Project No: 109T815), Ataturk University Scientific Research Project Council (Project Nos: 2010/32 and 2011/93) and Turkish Academy of Sciences is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.molcata.2013.06.013en_US
dc.identifier.endpage147en_US
dc.identifier.issn1381-1169
dc.identifier.issn1873-314X
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage142en_US
dc.identifier.urihttps://doi.org/10.1016/j.molcata.2013.06.013
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3957
dc.identifier.volume378en_US
dc.identifier.wosWOS:000324789600018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal Of Molecular Catalysis A-Chemicalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectZeolite-Yen_US
dc.subjectOsmium nanoclustersen_US
dc.subjectReusable catalysten_US
dc.subjectHydroperoxideen_US
dc.subject1,2,3-triolsen_US
dc.titleOne-pot synthesis of 1,2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium(0) nanoclustersen_US
dc.typeArticleen_US

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