Chemoselective hydrogenation of aromatic nitro compounds in the presence of homogeneous Pd based catalysts

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dc.contributor.authorZengin, Nursefa
dc.contributor.authorGoksu, Haydar
dc.contributor.authorSen, Fatih
dc.date.accessioned2021-12-01T18:47:45Z
dc.date.available2021-12-01T18:47:45Z
dc.date.issued2021
dc.department[Belirlenecek]en_US
dc.description.abstractThe chemoselective reduction of aromatic nitro compounds to amine derivatives was easily performed with remarkable yields under ultrasonic conditions in a H2O/MeOH mixture (v/v = 1/4). In this process, commercially available BINAP.PdCl2 and NaBH4 were used as homogenous catalysts and the hydrogen source, respectively. The developed method has a high economic value and can be adapted to the industry. A variety of nitroarene derivatives were reacted by undergoing the BINAP.PdCl2 catalyzed reduction reaction. All nitroarenes were selectively hydrogenated to aromatic primary amines with quantitative yields in 15 min. The obtained primary amines were determined by 1H and 13C nuclear magnetic resonance spectroscopy.en_US
dc.description.sponsorshipDuzce University Research FundDuzce University [2019.26.04.1019]en_US
dc.description.sponsorshipThis research was supported by the Duzce University Research Fund (grant no. 2019.26.04.1019) .en_US
dc.identifier.doi10.1016/j.chemosphere.2021.130887
dc.identifier.issn0045-6535
dc.identifier.issn1879-1298
dc.identifier.pmid34087559en_US
dc.identifier.scopus2-s2.0-85107147175en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.chemosphere.2021.130887
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10365
dc.identifier.volume282en_US
dc.identifier.wosWOS:000698193400005en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofChemosphereen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAniline derivativesen_US
dc.subjectHomogeneous catalysten_US
dc.subjectHydrogenationen_US
dc.subjectNitroareneen_US
dc.subjectRecyclable Heterogeneous Catalysten_US
dc.subjectAluminum Oxy-Hydroxideen_US
dc.subjectSelective Hydrogenationen_US
dc.subjectReductionen_US
dc.subjectNanoparticlesen_US
dc.subjectNitroarenesen_US
dc.subjectEfficienten_US
dc.subjectComplexen_US
dc.subjectMetalen_US
dc.subjectAminationen_US
dc.titleChemoselective hydrogenation of aromatic nitro compounds in the presence of homogeneous Pd based catalystsen_US
dc.typeArticleen_US

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