A facile synthesis of vicinal cis-diols from olefins catalyzed by in situ generated MnxOy nanoaggregates

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dc.contributor.authorDalmızrak, Diğdem
dc.contributor.authorGöksu, Haydar
dc.contributor.authorGültekin, Mehmet Serdar
dc.date.accessioned2020-04-30T22:38:39Z
dc.date.available2020-04-30T22:38:39Z
dc.date.issued2015
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.descriptionWOS: 000350221600019en_US
dc.description.abstractA novel protocol for the practical and green synthesis of vicinal cis-diols from 10.0 mmol olefins by using 5.0 mmol KMnO4 as oxidant and 30.0 mmol H2O2 as co-oxidant is reported. The presented procedure is easy to carry out and enables the direct transformation of linear and cyclic alkenes to the corresponding vicinal cis-diols. The synthesis of vicinal cis-diols by dihydroxylation of olefins with a KMnO4/H2O2 system was catalyzed by in situ generatedMnxOy nanoaggregates. The use of H2O2 as a co-oxidant is the key for the protocol to synthesize vicinal cis-diols in high yields, because it assists the oxidation of MnxOy nanoaggregates, which have an active role in the oxidation reaction medium.en_US
dc.description.sponsorshipAtaturk UniversityAtaturk University [2013/82]en_US
dc.description.sponsorshipWe thank Assoc. Prof. Dr Onder Metin for his help with the TEM, SEM, XRD, XPS, EDX, BET and BJT studies and proofreading. This work was supported by the Ataturk University under project no. 2013/82.en_US
dc.identifier.doi10.1039/c5ra01646ken_US
dc.identifier.endpage20755en_US
dc.identifier.issn2046-2069
dc.identifier.issue27en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage20751en_US
dc.identifier.urihttps://doi.org/10.1039/c5ra01646k
dc.identifier.urihttps://hdl.handle.net/20.500.12684/2348
dc.identifier.volume5en_US
dc.identifier.wosWOS:000350221600019en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofRsc Advancesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleA facile synthesis of vicinal cis-diols from olefins catalyzed by in situ generated MnxOy nanoaggregatesen_US
dc.typeArticleen_US

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