New Energetic Copper(II) Complexes With Pyrazolyl Type Ligands

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dc.contributor.authorÖz, Sevi
dc.contributor.authorSvoboda, Ingrid
dc.contributor.authorKurtaran, Raif
dc.contributor.authorAksu, Mecit
dc.contributor.authorSarı, Musa
dc.contributor.authorKunduracı, Melike
dc.contributor.authorAtakol, Orhan
dc.date.accessioned2020-04-30T23:19:32Z
dc.date.available2020-04-30T23:19:32Z
dc.date.issued2011
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionAksu, Mecit/0000-0002-9864-727Xen_US
dc.descriptionWOS: 000287942300013en_US
dc.description.abstractNine Cu-II complexes (I-IX) containing the azide ion and bis-2,6-(pyrazol-1-yl)pyridine (pp), bis-2,6-(pyrazol-1-yl)pyridine (dmpp), and 2-(pyrazol-1-yl)-6-(3,5-dirnethylpyrazol-1-yl)pyridine (mpp), which are derivatives of pyrazolylpyridine, were prepared in nonaqueous medium. These complexes were characterized by elemental analyses and IR spectroscopy. Crystals of one of these complexes [CumppClN(3) (VII)] were prepared in suitable size, and a molecular structure of this complex was obtained with X-ray diffraction method. Complexes were examined by thermogravimetry and differential scanning calorimetry methods. Thermal decomposition was observed in complexes including two azide groups similar to that seen in explosives. In the complexes containing one azide group, formation of the Cu-1 complexes was observed after thermal decomposition of the azide group.en_US
dc.description.sponsorshipAnkara University Research FundAnkara University [07B4240001]en_US
dc.description.sponsorshipThe authors thank to acknowledge the financial support of the Ankara University Research Fund (Project No: 07B4240001)en_US
dc.identifier.doi10.1002/zaac.201000276en_US
dc.identifier.endpage262en_US
dc.identifier.issn0044-2313
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage257en_US
dc.identifier.urihttps://doi.org/10.1002/zaac.201000276
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3782
dc.identifier.volume637en_US
dc.identifier.wosWOS:000287942300013en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThermochemistryen_US
dc.subjectPyrazolyl complexesen_US
dc.subjectAzido explosivesen_US
dc.subjectEnergetic compoundsen_US
dc.subjectCopperen_US
dc.titleNew Energetic Copper(II) Complexes With Pyrazolyl Type Ligandsen_US
dc.typeArticleen_US

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