New Energetic Copper(II) Complexes With Pyrazolyl Type Ligands
Yükleniyor...
Dosyalar
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-V C H Verlag Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Nine Cu-II complexes (I-IX) containing the azide ion and bis-2,6-(pyrazol-1-yl)pyridine (pp), bis-2,6-(pyrazol-1-yl)pyridine (dmpp), and 2-(pyrazol-1-yl)-6-(3,5-dirnethylpyrazol-1-yl)pyridine (mpp), which are derivatives of pyrazolylpyridine, were prepared in nonaqueous medium. These complexes were characterized by elemental analyses and IR spectroscopy. Crystals of one of these complexes [CumppClN(3) (VII)] were prepared in suitable size, and a molecular structure of this complex was obtained with X-ray diffraction method. Complexes were examined by thermogravimetry and differential scanning calorimetry methods. Thermal decomposition was observed in complexes including two azide groups similar to that seen in explosives. In the complexes containing one azide group, formation of the Cu-1 complexes was observed after thermal decomposition of the azide group.
Açıklama
Aksu, Mecit/0000-0002-9864-727X
WOS: 000287942300013
WOS: 000287942300013
Anahtar Kelimeler
Thermochemistry, Pyrazolyl complexes, Azido explosives, Energetic compounds, Copper
Kaynak
Zeitschrift Fur Anorganische Und Allgemeine Chemie
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
637
Sayı
2
