Homogeneous catalyst containing Pd in the reduction of aryl azides to primary amines

dc.contributor.authorCantopcu, E.
dc.contributor.authorAydınlı, Elif
dc.contributor.authorGöksu, Haydar
dc.date.accessioned2023-07-26T11:55:27Z
dc.date.available2023-07-26T11:55:27Z
dc.date.issued2022
dc.departmentDÜ, Kaynaşlı Meslek Yüksekokuluen_US
dc.description.abstractCommercially available dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) (BINAP center dot PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. The reactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydride was used as the reducing reagent. A number of aryl azide derivatives have been converted into primary amines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.en_US
dc.description.sponsorshipDuzce University Research Fund [2021.26.07.1180]en_US
dc.description.sponsorshipThis research was supported by Duzce University Research Fund (grant no. 2021.26.07.1180).en_US
dc.identifier.doi10.1007/s12039-022-02032-6
dc.identifier.issn0974-3626
dc.identifier.issn0973-7103
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85126179877en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1007/s12039-022-02032-6
dc.identifier.urihttps://hdl.handle.net/20.500.12684/13075
dc.identifier.volume134en_US
dc.identifier.wosWOS:000767929100002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorCantopcu, E.
dc.institutionauthorAydınlı, Elif
dc.institutionauthorGöksu, Haydar
dc.language.isoenen_US
dc.publisherIndian Acad Sciencesen_US
dc.relation.ispartofJournal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz$2023V1Guncelleme$en_US
dc.subjectAryl Azides; Hydrogenation; Primary Amines; Binap Center Dot Pdcl2en_US
dc.subjectChemoselective Hydrogenation; Carbonyl-Compounds; Nanoparticlesen_US
dc.titleHomogeneous catalyst containing Pd in the reduction of aryl azides to primary aminesen_US
dc.typeArticleen_US

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