Homogeneous catalyst containing Pd in the reduction of aryl azides to primary amines
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Dosyalar
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Indian Acad Sciences
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Commercially available dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) (BINAP center dot PdCl2) homogeneous catalyst was used for the reduction of aryl azides to primary amines. The reactions were carried out in water and yields above 95% were obtained in a short time. Sodium borohydride was used as the reducing reagent. A number of aryl azide derivatives have been converted into primary amines, thanks to the hydrogen gas released by sodium borohydride with the help of water and catalyst.
Açıklama
Anahtar Kelimeler
Aryl Azides; Hydrogenation; Primary Amines; Binap Center Dot Pdcl2, Chemoselective Hydrogenation; Carbonyl-Compounds; Nanoparticles
Kaynak
Journal of Chemical Sciences
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
134
Sayı
2
