Graphene aerogel-supported Na3V2(PO4)3/C cathodes for sodium-ion batteries

Basit Öğe Kaydı
dc.authoridAKBULUT, Hatem/0000-0002-6299-136Xen_US
dc.authoridguler, aslıhan/0000-0002-5155-2214en_US
dc.authoridSingil, Mustafa Mahmut/0000-0002-7666-8918en_US
dc.authorscopusid58604686400en_US
dc.authorscopusid57034927900en_US
dc.authorscopusid57442986900en_US
dc.authorscopusid57203584519en_US
dc.authorscopusid57201131288en_US
dc.authorscopusid58157073100en_US
dc.authorscopusid7005749968en_US
dc.authorwosidAKBULUT, Hatem/AAQ-4909-2020en_US
dc.authorwosidUZUN, ESMA/KMC-8801-2024en_US
dc.authorwosidSingil, Mustafa Mahmut/HTM-0086-2023en_US
dc.authorwosidguler, aslıhan/GZG-4499-2022en_US
dc.contributor.authorGultekin, Sidika Yildirim
dc.contributor.authorGuler, Aslihan
dc.contributor.authorKuruahmet, Deniz
dc.contributor.authorGungor, Hatice
dc.contributor.authorSingil, Mustafa Mahmut
dc.contributor.authorUzun, Esma
dc.contributor.authorAkbulut, Hatem
dc.date.accessioned2024-08-23T16:04:50Z
dc.date.available2024-08-23T16:04:50Z
dc.date.issued2023en_US
dc.departmentDüzce Üniversitesien_US
dc.description.abstractNa3V2(PO4)3 (NVP) is a preferred cathode material for Na-ion batteries due to its good thermal stability and long cycle life, but its low electrical conductivity limits its use. The carbon coating method is widely available in the literature but can solve the problem to a limited extent. Graphene aerogel-based composite materials with lightweight, high surface area and 3-dimensional (3D) porous structure are prepared, and the properties are tried to be improved further. In this study, carbon-coated Na3V2(PO4)3 (NVP/C) and graphene aerogel-carbon-coated Na3V2(PO4)3 (GA-NVP/C) composite have been synthesized. The produced samples have been analyzed using Field emission scanning electron microscopy, X-ray diffraction, Raman spectrum, Thermal Gravity Analysis, Xray photoelectron spectroscopy, Brunauer-Emmett-Teller and Transmission electron microscopy. Then, the effect of graphene aerogel additive on electrochemical performances as cathode materials has been investigated. Even though GA-NVP/C and NVP/C have similar discharge capacities in the first cycle, GA-NVP/C shows high cycle stability when compared to NVP/C after 250 cycles. The GA-NVP/C cathode also has a higher discharge capacity than the NVP/C cathode at different current rates. The diffusion coefficient calculated using the cyclic voltammetry curve of GA-NVP/C is also high, supporting the graphene aerogel's positive results. In conclusion, we show that adding GA with a 3-dimensional porous structure greatly improves the electrochemical properties of the cathode in Na-ion batteries.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [315M535]en_US
dc.description.sponsorshipAll the resources used in this study were supplied by the Scientific and Technological Research Council of Turkey (TUBITAK) under contract number 315M535-Na-ion Batteries: A Cheap Solution for Energy Storage and Conversion (STORENERGY). The authors gratefully thank this support.en_US
dc.identifier.doi10.1016/j.diamond.2023.110399
dc.identifier.issn0925-9635
dc.identifier.issn1879-0062
dc.identifier.scopus2-s2.0-85171620705en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.diamond.2023.110399
dc.identifier.urihttps://hdl.handle.net/20.500.12684/14386
dc.identifier.volume139en_US
dc.identifier.wosWOS:001083150800001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofDiamond And Related Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSodium -ion batteriesen_US
dc.subjectGraphene aerogelen_US
dc.subjectCathodeen_US
dc.subjectCarbon-Coated Na3v2(Po4)(3)en_US
dc.subjectHigh-Performance Cathodeen_US
dc.subjectElectrochemical Performanceen_US
dc.subjectPyrophosphate Cathodeen_US
dc.subjectElectrode Materialen_US
dc.subjectFacile Synthesisen_US
dc.subjectRate Capabilityen_US
dc.subjectRecent Progressen_US
dc.subjectAnode Materialsen_US
dc.subjectHigh-Capacityen_US
dc.titleGraphene aerogel-supported Na3V2(PO4)3/C cathodes for sodium-ion batteriesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu