Flexible arene ruthenium metalla-prisms
dc.contributor.author | Orhan, Ersin | |
dc.contributor.author | Garci, Amine | |
dc.contributor.author | Therrien, Bruno | |
dc.date.accessioned | 2020-05-01T12:10:05Z | |
dc.date.available | 2020-05-01T12:10:05Z | |
dc.date.issued | 2015 | |
dc.department | DÜ, Fen-Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.description | orhan, ersin/0000-0002-5461-1005; Therrien, Bruno/0000-0002-0388-2745 | en_US |
dc.description | WOS: 000363867500002 | en_US |
dc.description.abstract | Cationic arene ruthenium metalla-prisms of the general formula [Ru-6(p-cymene)(6)(tpmtt)(2)(OO boolean AND OO)(3)](6+) (tpmtt = 1,3,5-tris(pyridin-4-ylmethyl)-1,3,5-triazinane-2,4,6-trione) have been obtained from the corresponding dinuclear arene ruthenium complexes [Ru-2(p-cymene)(2)(OO boolean AND OO)Cl-2] (OO boolean AND OO = oxalato (ox), 2,5-dioxido-1,4-benzoquinonato (dobq), 2,5-dichloro-1,4-benzoquinonato (dClbq), 2,5-dioxido-3-undecyl-1,4-benzoquinonato (dubq), 5,8-dioxido-1,4-naphtoquinonato (donq)) by reaction with the tridentate tpmtt ligand and silver trifluoromethanesulfonate. These cationic arene ruthenium metalla-prisms have been isolated and characterized as their triflate salts. Upon formation of the metalla-prisms, the two tpmtt panels are in close proximity and do not allow encapsulation of guest molecules. (C) 2015 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Swiss National Science FoundationSwiss National Science Foundation (SNSF) [200020_152552]; University of Neuchatel | en_US |
dc.description.sponsorship | Financial support of this work by the Swiss National Science Foundation (200020_152552) is gratefully acknowledged. E.O. thanks the Duzce University for a sabbatical leave and the University of Neuchatel for financial support. | en_US |
dc.identifier.doi | 10.1016/j.ica.2015.09.002 | en_US |
dc.identifier.endpage | 9 | en_US |
dc.identifier.issn | 0020-1693 | |
dc.identifier.issn | 1873-3255 | |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 5 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2015.09.002 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12684/5983 | |
dc.identifier.volume | 438 | en_US |
dc.identifier.wos | WOS:000363867500002 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Science Sa | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Arene ligand | en_US |
dc.subject | Ruthenium | en_US |
dc.subject | Metalla-assemblies | en_US |
dc.subject | Supramolecular chemistry | en_US |
dc.subject | Half-sandwich complexes | en_US |
dc.title | Flexible arene ruthenium metalla-prisms | en_US |
dc.type | Article | en_US |
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