Flexible arene ruthenium metalla-prisms

dc.contributor.authorOrhan, Ersin
dc.contributor.authorGarci, Amine
dc.contributor.authorTherrien, Bruno
dc.date.accessioned2020-05-01T12:10:05Z
dc.date.available2020-05-01T12:10:05Z
dc.date.issued2015
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionorhan, ersin/0000-0002-5461-1005; Therrien, Bruno/0000-0002-0388-2745en_US
dc.descriptionWOS: 000363867500002en_US
dc.description.abstractCationic arene ruthenium metalla-prisms of the general formula [Ru-6(p-cymene)(6)(tpmtt)(2)(OO boolean AND OO)(3)](6+) (tpmtt = 1,3,5-tris(pyridin-4-ylmethyl)-1,3,5-triazinane-2,4,6-trione) have been obtained from the corresponding dinuclear arene ruthenium complexes [Ru-2(p-cymene)(2)(OO boolean AND OO)Cl-2] (OO boolean AND OO = oxalato (ox), 2,5-dioxido-1,4-benzoquinonato (dobq), 2,5-dichloro-1,4-benzoquinonato (dClbq), 2,5-dioxido-3-undecyl-1,4-benzoquinonato (dubq), 5,8-dioxido-1,4-naphtoquinonato (donq)) by reaction with the tridentate tpmtt ligand and silver trifluoromethanesulfonate. These cationic arene ruthenium metalla-prisms have been isolated and characterized as their triflate salts. Upon formation of the metalla-prisms, the two tpmtt panels are in close proximity and do not allow encapsulation of guest molecules. (C) 2015 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipSwiss National Science FoundationSwiss National Science Foundation (SNSF) [200020_152552]; University of Neuchatelen_US
dc.description.sponsorshipFinancial support of this work by the Swiss National Science Foundation (200020_152552) is gratefully acknowledged. E.O. thanks the Duzce University for a sabbatical leave and the University of Neuchatel for financial support.en_US
dc.identifier.doi10.1016/j.ica.2015.09.002en_US
dc.identifier.endpage9en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2015.09.002
dc.identifier.urihttps://hdl.handle.net/20.500.12684/5983
dc.identifier.volume438en_US
dc.identifier.wosWOS:000363867500002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectArene liganden_US
dc.subjectRutheniumen_US
dc.subjectMetalla-assembliesen_US
dc.subjectSupramolecular chemistryen_US
dc.subjectHalf-sandwich complexesen_US
dc.titleFlexible arene ruthenium metalla-prismsen_US
dc.typeArticleen_US

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