Novel bionanocomposites of chitosan-based blend containing LaB6: Thermal, dielectric, and biological properties

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dc.authorscopusid7003661021en_US
dc.authorscopusid35603667700en_US
dc.authorscopusid35791444100en_US
dc.authorscopusid6603118192en_US
dc.authorwosidaksu, mecit/J-5404-2012en_US
dc.contributor.authorErol, Ibrahim
dc.contributor.authorHazman, Omer
dc.contributor.authorAksu, Mecit
dc.contributor.authorUygur, Ilyas
dc.date.accessioned2024-08-23T16:07:17Z
dc.date.available2024-08-23T16:07:17Z
dc.date.issued2023en_US
dc.departmentDüzce Üniversitesien_US
dc.description.abstractIn the presented study, a strategy that will offer alternative usage areas by strengthening the physicochemical properties of the green polymer chitosan (CS) is aimed. For this purpose, a compatible blend of CS (CS-PFPAMA) with poly 2-(4-fluorophenyl)-2-oxoethyl-2-methylprop-2-enoate (PFPAMA), a methacrylate-based synthetic polymer, was prepared by hydrothermal method. Miscibility and compatibility of the CS-PFPAMA blend were confirmed by the single glass transition temperature (T-g) determined by differential scanning calorimetry (DSC). Then, lanthanum hexaboride (LaB6) nanoparticles (NPs) prepared by the chemical method were successfully added to the CS-PFPAMA blend at different weight ratios by hydrothermal method. Morphological characterizations of CS-PFPAMA blend and produced nanocomposites were performed with Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy, and atomic force microscopy, and thermal characterizations were made with thermogravimetric analysis and DSC. The thermal stability and T-g values of the obtained CS-PFPAMA blend and nanocomposites were lower than the values of the CS. However, LaB6 NPs increased the dielectric properties of the CS-PFPAMA blend. Thus, the potential use of the produced nanocomposites in electronic devices may be in question. According to the results of antibiogram tests performed by the disk diffusion method, it was determined that nanocomposites showed a serious resistance against Escherichia coli and Staphylococcus aureus pathogens. In addition, both antioxidant and oxidant properties of nanocomposites showed values close to the reference material used. The determined biological properties indicate that the CS-based nanocomposites can be used as biomaterials.en_US
dc.description.sponsorshipAfyon Kocatepe University Scientific Research Projects Coordination Unit [FENED.12]en_US
dc.description.sponsorshipACKNOWLEDGMENTS This study has been supported by the Afyon Kocatepe University Scientific Research Projects Coordination Unit. The Project Number is 12.FENED.12.en_US
dc.identifier.doi10.1002/pat.6085
dc.identifier.endpage2738en_US
dc.identifier.issn1042-7147
dc.identifier.issn1099-1581
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85159292698en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2721en_US
dc.identifier.urihttps://doi.org/10.1002/pat.6085
dc.identifier.urihttps://hdl.handle.net/20.500.12684/14573
dc.identifier.volume34en_US
dc.identifier.wosWOS:000988413900001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofPolymers For Advanced Technologiesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectantibacterial propertiesen_US
dc.subjectchitosanen_US
dc.subjectmethacrylateen_US
dc.subjectnanocompositesen_US
dc.subjectMonomer Reactivity Ratiosen_US
dc.subjectMethacrylate Polymeren_US
dc.subjectSilver Nanoparticlesen_US
dc.subjectZno Nanoparticlesen_US
dc.subjectIn-Vitroen_US
dc.subjectMiscibilityen_US
dc.subjectStabilityen_US
dc.subjectEnergyen_US
dc.titleNovel bionanocomposites of chitosan-based blend containing LaB6: Thermal, dielectric, and biological propertiesen_US
dc.typeArticleen_US

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