Synthesis and Characterization of Poly(N-Isopropyl Acryl Amide)-g-Poly(Linoleic Acid)/Poly(Linolenic Acid) Graft Copolymers

Basit Öğe Kaydı
dc.contributor.authorAllı, Abdulkadir
dc.contributor.authorHazer, Baki
dc.date.accessioned2020-04-30T23:32:26Z
dc.date.available2020-04-30T23:32:26Z
dc.date.issued2011
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000287360700009en_US
dc.description.abstractTo diversify edible oil thermoresponsive polymer composites, polymeric linoleic acid peroxide (PLina) and polymeric linolenic acid peroxide (PLinl) were obtained by the autoxidation of linoleic acid (Lina) and linolenic acid (Linl), respectively. The autoxidation of Lina and Linl under air at room temperature rendered waxy soluble polymeric peroxide, having a soluble fraction in chloroform of more than 91 wt% and containing up to 1.0 wt% of peroxide. The soluble polymeric oil macro-peroxide was used to initiate the free radical polymerization of N-isopropylacrylamide, NIPAM, resulting in PLina-g-PNIPAM and PLinl-g-PNIPAM graft copolymers, respectively. The PNIPAM content of the graft copolymers was calculated using the elemental nitrogen analysis of graft copolymers. Thermal analysis, FTIR, (1)H NMR, and SEM techniques were used in the characterization of the products. The hydrophobic effect of the fatty acid macro peroxides on the thermal response rate of the graft copolymers was investigated by means of swelling-deswelling behaviors in response to temperature change. They have a thermoresponsive character and exhibit a volume phase transition at approximately 27-30 A degrees C, which is 1-4 A degrees C lower than that of pure PNIPAM. A plastizer effect of PLina and PLinl in graft copolymers was observed, indicating a lower glass transition temperature than that of pure PNIPAM.en_US
dc.description.sponsorshipTUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [109T029, 108T423]; Zonguldak Karaelmas UniversityBulent Ecevit University [2008-70-01-01]; Duzce UniversityDuzce Universityen_US
dc.description.sponsorshipThis work was financially supported by TUBITAK (grant nos. 109T029 and 108T423), Zonguldak Karaelmas University Research Fund (grant no. 2008-70-01-01), and Duzce University Research Fund.en_US
dc.identifier.doi10.1007/s11746-010-1663-1en_US
dc.identifier.endpage263en_US
dc.identifier.issn0003-021X
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage255en_US
dc.identifier.urihttps://doi.org/10.1007/s11746-010-1663-1
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4717
dc.identifier.volume88en_US
dc.identifier.wosWOS:000287360700009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of The American Oil Chemists Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAutoxidationen_US
dc.subjectLinoleic aciden_US
dc.subjectLinolenic aciden_US
dc.subjectN-isopropylacrylamideen_US
dc.subjectGraft copolymeren_US
dc.titleSynthesis and Characterization of Poly(N-Isopropyl Acryl Amide)-g-Poly(Linoleic Acid)/Poly(Linolenic Acid) Graft Copolymersen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
4717.pdf
Boyut:
453.18 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu