Nitroxide-mediated copolymerization of styrene and pentafluorostyrene initiated by polymeric linoleic acid

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dc.contributor.authorAllı, Abdulkadir
dc.contributor.authorAllı, Sema
dc.contributor.authorBecer, C. Remzi
dc.contributor.authorHazer, Baki
dc.date.accessioned2020-04-30T23:19:38Z
dc.date.available2020-04-30T23:19:38Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionBecer, C. Remzi/0000-0003-0968-6662en_US
dc.descriptionWOS: 000369845000016en_US
dc.description.abstractPolymeric linoleic asit graft copolymers were synthesized via a nitroxide-mediated radical polymerization (NMRP) method in the presence of 2,2-6,6-tetramethylpiperidinyl-1-oxy (TEMPO). For this purpose, PLina-ox was exposed to polymerization with styrene (Sty) or Sty and pentafluorostyrene (F5Sty) in the presence of TEMPO by NMRP method in order to obtain PLina-g-PSty and PLina-g-PF5Sty-g-PSty graft copolymers with controlled structure and low polydispersity. Chain extension study was evaluated. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the polymerization reactions, were evaluated. The products thus obtained were well characterized by H-1 NMR, GPC, and F-19 NMR measurements. Practical application: We report for the first time the synthesis of PLina-g-PSty and PLina-g-PSty-g-PF5Sty graft copolymers in the presence of TEMPO. NMRPreactions were performed in the presence of TEMPO in order to obtain graft copolymers with controlled molecular weight and polydispersity. Chain-extension reactions were also successfully carried out because of the activation of TEMPO terminated chain ends of graft copolymers. Pure linoleic acid was auto-oxidized under daylight and air oxygen, yielding peroxidized PLina (PLina-ox). PLina-ox has been used in the polymerization of styrene (Sty) or copolymerization of Sty and pentafluorostyrene (F5Sty).en_US
dc.description.sponsorshipBulent Ecevit UniversityBulent Ecevit University [BEU-2012-10-03-13]; Duzce UniversityDuzce University [2014.05.03.234, 2014.05.03.248]; Turkish Scientific Research Council, TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [211T016, 110T884]en_US
dc.description.sponsorshipThis work was supported financially by Bulent Ecevit University Research Fund (#BEU-2012-10-03-13), Duzce University Research Fund (grants numbers: 2014.05.03.234, 2014.05.03.248) and Turkish Scientific Research Council, TUBITAK, (grants numbers: 211T016, 110T884).en_US
dc.identifier.doi10.1002/ejlt.201500129en_US
dc.identifier.endpage287en_US
dc.identifier.issn1438-7697
dc.identifier.issn1438-9312
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage279en_US
dc.identifier.urihttps://doi.org/10.1002/ejlt.201500129
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3812
dc.identifier.volume118en_US
dc.identifier.wosWOS:000369845000016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofEuropean Journal Of Lipid Science And Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAutoxidationen_US
dc.subjectLinoleic aciden_US
dc.subjectNitroxide-mediated radical polymerizationen_US
dc.subjectPentafluorostyreneen_US
dc.titleNitroxide-mediated copolymerization of styrene and pentafluorostyrene initiated by polymeric linoleic aciden_US
dc.typeArticleen_US

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