Synthesis of benzimidazole moiety heteroleptic ruthenium complex and use as sensitizer in dye-sensitized solar cells

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dc.contributor.authorOrhan, Ersin
dc.contributor.authorGokcen, Muharrem
dc.contributor.authorTaran, Songul
dc.date.accessioned2021-12-01T18:47:06Z
dc.date.available2021-12-01T18:47:06Z
dc.date.issued2021
dc.department[Belirlenecek]en_US
dc.description.abstractThe new benzimidazole functional heteroleptic ruthenium complex dye (BRD) was prepared for dye-sensitized solar cells (DSSCs). The compound was identified by various spectroscopic techniques and photovoltaic performances of this BRD DSSC were investigated and compared with Z907 (cis-diisothiocyanato-(2,2 '-bipyridyl-4,4 '-dicarboxylic acid)-(2,2 '-bipyridyl-4,4 '-dinonyl) ruthenium(II)) DSSCs. It was found that [Ruthenium (4,4 '-dicarboxylic acid-2,2 '-bipyridine) (1-(2-ethoxyethyl)-2-(pyridine-2-yl)benzimidazole) (NCS)(2)] (2) has a thermal stability below 300 degrees C. Two different electrolytes were used to get the effect on photovoltaic parameters. The photovoltaic measurements of the BRD and Z907 DSSCs were carried out under 100 mW/cm(2) (AM1.5) illumination. Short-circuit current density (J(sc)) values were obtained as 8.20 and 7.32 mA/cm(2) for AN50 and HI30 electrolytes, respectively. The photovoltaic efficiencies were obtained as 3.03% and 2.82% for AN50 and HI30 electrolytes, respectively.en_US
dc.description.sponsorshipDuzce University Research FundDuzce University [2019.05.02.1026, 2020.05.02.1136, 2020.05.03.1143]en_US
dc.description.sponsorshipThis work is supported by Duzce University Research Fund Project Numbers: 2019.05.02.1026, 2020.05.02.1136, 2020.05.03.1143.en_US
dc.identifier.doi10.1007/s00339-021-05080-w
dc.identifier.issn0947-8396
dc.identifier.issn1432-0630
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85119050446en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1007/s00339-021-05080-w
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10142
dc.identifier.volume127en_US
dc.identifier.wosWOS:000718851300003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofApplied Physics A-Materials Science & Processingen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRuthenium complexen_US
dc.subjectBenzimidazoleen_US
dc.subjectPhotovoltaicen_US
dc.subjectDye-sensitized solar cellen_US
dc.subjectDSSCen_US
dc.subjectRu(Ii) Complexesen_US
dc.subjectPerformanceen_US
dc.subjectCobalten_US
dc.subjectElectrolyteen_US
dc.subjectLigandsen_US
dc.subjectCopperen_US
dc.titleSynthesis of benzimidazole moiety heteroleptic ruthenium complex and use as sensitizer in dye-sensitized solar cellsen_US
dc.typeArticleen_US

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