Coordination-driven self-assembly of arene ruthenium metalla-rectangles

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dc.contributor.authorOrhan, Ersin
dc.contributor.authorGarci, Amine
dc.contributor.authorTherrien, Bruno
dc.date.accessioned2020-04-30T22:41:45Z
dc.date.available2020-04-30T22:41:45Z
dc.date.issued2017
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionTherrien, Bruno/0000-0002-0388-2745en_US
dc.descriptionWOS: 000399712200012en_US
dc.description.abstractSeries of tetranuclear arene ruthenium complexes of the general formula [Ru-4(p-cymene)(4)(mu(2)-N boolean AND N)(2) (mu(4)-OO boolean AND OO2][CF3SO3](4) (N boolean AND N = 2,5- dipyridyl-thiophene (dptp), 3,6-dipyridyl-1,2,4,5-tetrazine (dptz), 3,6-dipyridyl-1,4-dihydro-1,2,4,5-tetrazine (dpdt)) were prepared by reacting the dinuclear arene ruthenium complexes Ru-2(p-cymene)(2)(mu(4)-OO boolean AND OO)Cl-2 (OO boolean AND OO = oxalato (oxa), 2,5-dioxido-1,4-benzoquinonato (dobq), 2,5-dichloro-1,4-benzoquinonato (dClbq), 2,5-dioxido-3-undecyl-1,4-benzoquinonato (dubq), 5,8-dioxido-1,4-naphtoquinonato (donq)) with silver trifluoromethanesulfonate, followed by the addition of the corresponding N boolean AND N linkers. All metalla-rectangles were characterized by standard techniques, including infrared, UV-visible, H-1, C-13 NMR spectroscopy and ESI mass spectrometry: Thus confirming the rectangular structure of the complexes, and showing the facility of forming tetranuclear arene ruthenium metalla-rectangles. (C) 2017 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipUniversity of Neuchatelen_US
dc.description.sponsorshipE. O. thanks the Duzce University for a sabbatical leave and the University of Neuchatel for financial support.en_US
dc.identifier.doi10.1016/j.ica.2017.01.033en_US
dc.identifier.endpage83en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage78en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2017.01.033
dc.identifier.urihttps://hdl.handle.net/20.500.12684/3243
dc.identifier.volume461en_US
dc.identifier.wosWOS:000399712200012en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSupramolecular chemistryen_US
dc.subjectArene ruthenium complexesen_US
dc.subjectMetalla-assembliesen_US
dc.subjectMetalla-rectanglesen_US
dc.subjectHalf-sandwich complexesen_US
dc.titleCoordination-driven self-assembly of arene ruthenium metalla-rectanglesen_US
dc.typeArticleen_US

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