Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant
Yükleniyor...
Dosyalar
Tarih
2016
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Acg Publications
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the corresponding allylic hydroperoxide at different temperatures (0 degrees C and room temperature) with potassium permanganate (KMnO4) in mild condition at N-2(g) atm.
Açıklama
WOS: 000411597000004
Anahtar Kelimeler
Allylic hydroperoxide, singlet oxygen, photooxygenation, eugenol, natural product
Kaynak
Organic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
9
Sayı
4
