A combined electrochemical and theoretical study into the effect of 2-((thiazole-2-ylimino)methyl)phenol as a corrosion inhibitor for mild steel in a highly acidic environment

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dc.contributor.authorYılmaz, Nurdane
dc.contributor.authorFitoz, Alper
dc.contributor.authorErgun, Ümit
dc.contributor.authorEmregül, Kaan C.
dc.date.accessioned2020-04-30T22:38:37Z
dc.date.available2020-04-30T22:38:37Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionEmregul, Kaan C/0000-0002-2991-9702en_US
dc.descriptionWOS: 000382794000010en_US
dc.description.abstract2-((Thiazole-2-ylimino)methyl)phenol (THYMP) was studied as a corrosion inhibitor for the protection of mild steel in 2 M HCl solution by means of weight loss, polarization, electrochemical impedance spectroscopy and scanning electron microscopy. The potential of zero charge (E-pzc), was also determined for evaluation of the adsorption mechanism. Quantum chemical parameters such as highest occupied molecular orbital energy (E-Homo), lowest unoccupied molecular orbital energy (E-Lumo), energy gap (Delta E), dipole moment (mu) etc. were calculated using density functional theory (DFT) at B3LYP/6-31G(d,p) level. Theoretical and experimental results were in fairly good agreement. (C) 2016 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipAnkara University Research FundAnkara University [15B0430001]en_US
dc.description.sponsorshipThe authors wish to acknowledge the financial support of the Ankara University Research Fund (Project No.: 15B0430001). The authors would also like to thank Dr. Ece ERGUN for her help and support in preparation of this manuscript.en_US
dc.identifier.doi10.1016/j.corsci.2016.05.002en_US
dc.identifier.endpage120en_US
dc.identifier.issn0010-938X
dc.identifier.issn1879-0496
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage110en_US
dc.identifier.urihttps://doi.org/10.1016/j.corsci.2016.05.002
dc.identifier.urihttps://hdl.handle.net/20.500.12684/2314
dc.identifier.volume111en_US
dc.identifier.wosWOS:000382794000010en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofCorrosion Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMild steelen_US
dc.subjectCorrosion inhibitoren_US
dc.subjectEISen_US
dc.subjectPolarizationen_US
dc.subjectSEMen_US
dc.subjectDFTen_US
dc.titleA combined electrochemical and theoretical study into the effect of 2-((thiazole-2-ylimino)methyl)phenol as a corrosion inhibitor for mild steel in a highly acidic environmenten_US
dc.typeArticleen_US

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