Synthesis of novel methacrylate-based nanocomposites containing ZnO via the hydrothermal method and determination of thermal, optical, and biocidal properties

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dc.authoridaksu, mecit/0000-0002-9864-727X
dc.authorwosidaksu, mecit/J-5404-2012
dc.contributor.authorErol, İbrahim
dc.contributor.authorAksu, Mecit
dc.contributor.authorGürler, Zeki
dc.date.accessioned2023-07-26T11:55:30Z
dc.date.available2023-07-26T11:55:30Z
dc.date.issued2022
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn this work, the hydrothermal method was used to prepare nanocomposites of a new methacrylate polymer (PFPAMA) carrying the aryl fluoro group in the side branch and containing different mass ratios (1%, 3%, and 5%) of nano ZnO. Morphological and structural properties of the PFPAMA-ZnO nanocomposites were determined via scanning electron microscope, transmission electron microscopy, Fourier transform infrared, ultraviolet (UV), and X-ray diffraction, whereas the thermal properties of the nanocomposites were determined using thermogravimetric analysis (TGA) and differential scanning calorimetry techniques. The obtained results showed that the thermal stability and glass transition temperature (T-g) of the nanocomposites had increased with the increase in the amount of ZnO. Thermal degradation activation energies (E-a) of the nanocomposites were calculated via non-isothermal TGA experiments using the Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose methods. Both calculated E-a values were compatible with each other and increased in parallel with the ZnO increases. The UV measurements showed that the ZnO nanoparticles added to the PFPAMA played an important role as a UV barrier, and thus expanding the potential applications of the PFPAMA polymer. Finally, the biological activities of the PFPAMA/ZnO nanocomposites against Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria were also tested.en_US
dc.description.sponsorshipAfyon Kocatepe University Scientific Research Projects Coordination Unit [21-FENED-05]en_US
dc.description.sponsorshipThis study was supported by the Afyon Kocatepe University Scientific Research Projects Coordination Unit (Project Number 21-FENED-05).en_US
dc.identifier.doi10.1002/app.53030
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue42en_US
dc.identifier.scopus2-s2.0-85135961930en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/app.53030
dc.identifier.urihttps://hdl.handle.net/20.500.12684/13086
dc.identifier.volume139en_US
dc.identifier.wosWOS:000851552100001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAksu, Mecit
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz$2023V1Guncelleme$en_US
dc.subjectAntimicrobial Activity; Hydrothermal Method; Pfpama; Zno Composite; Swelling Properties; Thermal Decomposition Kineticsen_US
dc.subjectZinc-Oxide; Poly(Methyl Methacrylate); Quantum Dots; Reactivity Ratios; Polymerization; Nanoparticles; Composites; Particles; Surface; Filmsen_US
dc.titleSynthesis of novel methacrylate-based nanocomposites containing ZnO via the hydrothermal method and determination of thermal, optical, and biocidal propertiesen_US
dc.typeArticleen_US

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