A practical and highly efficient reductive dehalogenation of aryl halides using heterogeneous Pd/AlO(OH) nanoparticles and sodium borohydride

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dc.contributor.authorKara, Belgüzar Yasemin
dc.contributor.authorYazıcı, Melike
dc.contributor.authorKılbaş, Benan
dc.contributor.authorGöksu, Haydar
dc.date.accessioned2020-04-30T22:38:48Z
dc.date.available2020-04-30T22:38:48Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000383300700009en_US
dc.description.abstractThe reductive dehalogenation of aryl halides was performed by using commercially available aluminium oxy-hydroxide-supported palladium (Pd/AlO(OH)) nanoparticles of about 3 nm size (0.5 wt. % Pd) with sodium borohydride. The dehalogenated products were obtained with absolute conversion in a mixture of H2O/MeOH (v/v=1/1) under ultrasonic conditions at room temperature. All aryl halides were successfully converted to halogen-free compounds within 1.5-4 h with yields of over 95%. The one-pot catalytic method is presented as a new process for the reductive dehalogenation of halogenated compounds. This method is quite simple, highly efficient and eco-friendly, and has an exceptional recovery rate. (C) 2016 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipDuzce University Research FundDuzce University [2014.05.03.243, 2015.26.04.371]en_US
dc.description.sponsorshipThis research was supported by Duzce University Research Fund (grant nos. 2014.05.03.243 and 2015.26.04.371).en_US
dc.identifier.doi10.1016/j.tet.2016.08.027en_US
dc.identifier.endpage5902en_US
dc.identifier.issn0040-4020
dc.identifier.issue39en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5898en_US
dc.identifier.urihttps://doi.org/10.1016/j.tet.2016.08.027
dc.identifier.urihttps://hdl.handle.net/20.500.12684/2458
dc.identifier.volume72en_US
dc.identifier.wosWOS:000383300700009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPdAlO(OH)en_US
dc.subjectHeterogeneous catalysten_US
dc.subjectDehalogenationen_US
dc.subjectReductionen_US
dc.subjectNaBH4en_US
dc.titleA practical and highly efficient reductive dehalogenation of aryl halides using heterogeneous Pd/AlO(OH) nanoparticles and sodium borohydrideen_US
dc.typeArticleen_US

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