A practical and highly efficient transfer hydrogenation of aryl azides using a [Ru(p-cymene)Cl-2](2) catalyst and sodium borohydride
Yükleniyor...
Dosyalar
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier France-Editions Scientifiques Medicales Elsevier
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Various aniline derivatives were synthesized by selective reduction of aryl azides in the presence of a dichloro(p-cymene)ruthenium(II) dimer ([Ru(p-cymene)Cl-2](2)) via hydrolysis of sodium borohydride. The hydrogenation reactions were carried out in aqueous media at room temperature. Most of the reactions were completed within 10 min with quantitative yields. (C) 2018 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
Açıklama
Coleri, Sinem/0000-0002-7502-3122
WOS: 000453646100010
WOS: 000453646100010
Anahtar Kelimeler
[Ru(p-cymene)Cl-2](2 ), Homogeneous catalyst, Transfer hydrogenation, Aryl azide
Kaynak
Comptes Rendus Chimie
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
21
Sayı
9
