Synthesis, characterization, crystal structure, magnetic studies of a novel polymeric zig-zag chain copper (II) complex

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dc.contributor.authorYardan, Alper
dc.contributor.authorYahşi, Yasemin
dc.contributor.authorKara, Hülya
dc.contributor.authorKarahan, Ahmet
dc.contributor.authorDurmuş, Sefa
dc.contributor.authorKurtaran, Raif
dc.date.accessioned2020-04-30T23:32:29Z
dc.date.available2020-04-30T23:32:29Z
dc.date.issued2014
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptiondurmus, sefa/0000-0001-6974-513X; KARA, Hulya/0000-0002-2032-8930en_US
dc.descriptionWOS: 000332521000008en_US
dc.description.abstractA single crystal of copper (II) complex (1) has been synthesized and its crystal structure has been determined by single crystal X-ray diffraction analysis and characterized by elemental analyses, IR spectroscopy, thermal analysis, H-1 NMR and C-13 NMR spectroscopy. The complex crystallizes in orthorombic space group Pnma, with unit cell dimensions a = 9.8944, b = 25.2972, c = 7.4457 angstrom, ss = 90 degrees. Structural analysis of (1) shows that the Schiff base ligand coordinates toward one metal atom in a pentadentate mode and each Cu atom is six-coordinated. The aliphatic oxygen atom of Schiff base ligand links the [CuL] moieties and creates polymeric zig-zag chain structure. In addition, magnetic susceptibilities for complex (1) have been measured over the temperature range 2-300 K and the magnetic parameters have been determined with fitting procedure. Magnetic measurements on (1) reveal the presence of antiferromagnetic exchange interactions between Cu(II) ions in the dimeric unit via bridging oxygen atoms of pentadentate Schiff base ligand. (c) 2014 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-108T431]; TBAG-108T431 and Balikesir UniversityBalikesir University [2007/10]; Balikesir UniversityBalikesir University [2007/10]en_US
dc.description.sponsorshipThe financial support of the Scientific and Technical Research Council of Turkey (TUBITAK) Grants No: TBAG-108T431 and Balikesir University (Project No. 2007/10) is gratefully acknowledged. And Yasemin Yahsi is also grateful to Dr. Lorenzo Sorace, Dr. Andrea Caneschi and Laboratory of Molecular Magnetism (Department of Chemistry, University of Florence) for the use of Cryogenic S600 SQUID magnetometer and Xcalibur-3 diffractometer and helpful suggestions.en_US
dc.identifier.doi10.1016/j.ica.2014.01.006en_US
dc.identifier.endpage59en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage55en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2014.01.006
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4733
dc.identifier.volume413en_US
dc.identifier.wosWOS:000332521000008en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff basesen_US
dc.subjectCopper (II) complexen_US
dc.subjectThermal analysisen_US
dc.subjectSingle crystal X-rayen_US
dc.subjectMagnetic behavioren_US
dc.titleSynthesis, characterization, crystal structure, magnetic studies of a novel polymeric zig-zag chain copper (II) complexen_US
dc.typeArticleen_US

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