Selectivity and activity in catalytic hydrogenation of azido groups over Pd nanoparticles on aluminum oxy-hydroxide

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dc.contributor.authorKara, Belgüzar Yasemin
dc.contributor.authorKılbaş, Benan
dc.contributor.authorGöksu, Haydar
dc.date.accessioned2020-04-30T23:31:49Z
dc.date.available2020-04-30T23:31:49Z
dc.date.issued2016
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000387621500067en_US
dc.description.abstractAzidoarenes involving various functional groups were successfully reduced to aniline derivatives using commercially available aluminium oxy-hydroxide-supported palladium (Pd/AlO(OH)) nanoparticles ( 0.5 wt% Pd) in an aqueous medium with sodium borohydride as the hydrogen source. To develop the green process, water was utilized in conjunction with methanol. The results demonstrated that the halogen substituted azidoarenes were selectively converted to the corresponding aniline compounds without dehalogenation. In general, all of the reactions were completed within 10-30 min at room temperature with yields of over 99%. In order to optimize the reaction conditions, the parametric effects of the solvent type and the amount of the catalyst/NaBH4 were examined. Consequently, for the first time, a novel, practical and environmentally friendly process was developed for the conversion of azidoarenes to aniline derivatives in the fluence of Pd/AlO(OH) nanoparticles.en_US
dc.description.sponsorshipDuzce UniversityDuzce University [2014.05.03.243, 2015.26.04.371]en_US
dc.description.sponsorshipThis research was supported by Duzce University Research Fund (grant no. 2014.05.03.243 and 2015.26.04.371).en_US
dc.identifier.doi10.1039/c6nj01925ken_US
dc.identifier.endpage9555en_US
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.issue11en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage9550en_US
dc.identifier.urihttps://doi.org/10.1039/c6nj01925k
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4488
dc.identifier.volume40en_US
dc.identifier.wosWOS:000387621500067en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofNew Journal Of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSelectivity and activity in catalytic hydrogenation of azido groups over Pd nanoparticles on aluminum oxy-hydroxideen_US
dc.typeArticleen_US

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