Structure and thermal decomposition of mu-1,1-azido bridged dinuclear Fe(III) complexes

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dc.contributor.authorErcan, Filiz
dc.contributor.authorAteş, B. Meltem
dc.contributor.authorAksu, Levent
dc.contributor.authorSözeri, Hüseyin
dc.contributor.authorErcan, İsmail
dc.contributor.authorAtakol, Orhan
dc.date.accessioned2020-04-30T23:32:15Z
dc.date.available2020-04-30T23:32:15Z
dc.date.issued2007
dc.departmentDÜ, Teknik Eğitim Fakültesien_US
dc.descriptionErcan, ismail/0000-0001-6490-3792; Ercan, filiz/0000-0002-3533-0726;en_US
dc.descriptionWOS: 000249792800009en_US
dc.description.abstractFe(III) complexes were prepared by the reaction of two different ONNO type Schiff bases N,N'-bis (salicylidene)-1,3-propanediamine (LH2) and N,N'-bis (salicylidene)-2,2'-dimethyl-1,3-propane diamine (LDMH2) in N-3(-) containing medium. The X-ray diffraction studies revealed that the complexes are of dinuclear type connected with mu-1,1-azido bridges. It was observed from the thermogravimetric analyses of the complexes that the azide group decomposed around 200 degrees C with exothermic reaction. This exothermic decomposition did not affect the rest of the molecule. Following the decomposition of the azide group the remainder of the molecule decomposed with carbonization process. It was seen that the molecule decomposed into Fe2O3 above 650 degrees C in oxygen containing medium. [FeLDMN3](2) complex was found to have N4O2 distorted octahedral sphere with Fe...Fe distance of 3.414 angstrom.en_US
dc.identifier.doi10.1524/zkri.2007.222.9.498en_US
dc.identifier.endpage503en_US
dc.identifier.issn0044-2968
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage498en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.2007.222.9.498
dc.identifier.urihttps://hdl.handle.net/20.500.12684/4663
dc.identifier.volume222en_US
dc.identifier.wosWOS:000249792800009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherOldenbourg Verlagen_US
dc.relation.ispartofZeitschrift Fur Kristallographieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectdinuclear Fe(III) complexen_US
dc.subjectX-ray diffractionen_US
dc.subjectsingle crystal structure analysisen_US
dc.subjectmagnetic propertiesen_US
dc.subjectthermal analysisen_US
dc.titleStructure and thermal decomposition of mu-1,1-azido bridged dinuclear Fe(III) complexesen_US
dc.typeArticleen_US

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