Electrical properties of CsPbX3 (X=Cl, Br) perovskite quantum dot/poly (HEMA) cryogel nanocomposites
Yükleniyor...
Dosyalar
Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Quantum dot-filled polymer nanocomposites are recent of interest due to the improvement of the properties and possibility of use in diverse application areas. In this study, poly(HEMA) cryogels and CsPbCl3 and CsPbBr3 perovskite quantum dots were separately synthesized and then perovskite quantum dots/cryogel nanocomposites were formed for the first time. After comprehensive characterizations of the nanocomposites, the dielectric properties of those structures were studied using impedance spectroscopy. All characterization methods revealed the effective formation of the quantum dot/cryogel nanocomposites. The real part of the dielectric components of the nanocomposites decreased concerning the pure cryogel. For the CsPbCl3 quantum dots filled nanocomposites, the imaginary part of the dielectric component and the loss tangent parameter increased almost by the factors of similar to 1.8 and similar to 2.2, respectively. On the other hand, for the CsPbBr3 quantum dots filled cryogel, the imaginary part of the dielectric component and the loss tangent parameter values decreased by the factors of similar to 2.6 and similar to 2 respectively. The large dielectric losses in the case of CsPbCl3 quantum dot-based nanocomposite were attributed to the high existence of surface traps on the surface of the CsPbCl3 quantum dots.
Açıklama
Anahtar Kelimeler
Perovskite Quantum Dots; Poly(Hema); Nano-Composites; Electrical Properties, Nanocrystals; Hydrogels; Composites; Dispersion
Kaynak
Materials Chemistry and Physics
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
277
