Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone in the presence of potassium permanganate without a co-oxidant

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Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

ACG Publications

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the °C and room temperature) with potassium permanganate (KMnO4) in mild condition at N2(g) atm. © 2016 ACG Publications.

Açıklama

Anahtar Kelimeler

Allylic hydroperoxide; Eugenol; Natural product; Photooxygenation; Singlet oxygen

Kaynak

Organic Communications

WoS Q Değeri

Scopus Q Değeri

Q4

Cilt

9

Sayı

4

Künye