Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone in the presence of potassium permanganate without a co-oxidant
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Dosyalar
Tarih
2016
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ACG Publications
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the °C and room temperature) with potassium permanganate (KMnO4) in mild condition at N2(g) atm. © 2016 ACG Publications.
Açıklama
Anahtar Kelimeler
Allylic hydroperoxide; Eugenol; Natural product; Photooxygenation; Singlet oxygen
Kaynak
Organic Communications
WoS Q Değeri
Scopus Q Değeri
Q4
Cilt
9
Sayı
4