Synthesis and DFT study of Cd(II) and Hg(II) complexes of ONNO-type Schiff bases
Yükleniyor...
Dosyalar
Tarih
2017
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This study consists of the synthesis of cadmium (II) and mercury (II) metal complexes of ONNO-type Schiff bases. Two different ONNO-type Schiff bases were prepared. One cadmium(II) and one mercury(II) complex of the considered Schiff bases were achieved. Both are proved to be mononuclear complexes. Ligands and complexes were analyzed via melting point determination, elemental analyses, thermogravimetric (TG) analysis, infrared (IR) spectroscopy, and nuclear magnetic resonance (NMR) spectroscopy. Moreover, structural and energetic analyses for both complexes have been realized using Hartree-Fock (HF) and density functional theory (DFT) methods with CEP-121G basis set.
Açıklama
CIFCI, Mehmet Akif/0000-0002-6439-8826; Boyukata, Mustafa/0000-0002-1117-2620; Aksu, Mecit/0000-0002-9864-727X; Babgi, Bandar/0000-0002-9364-263X
WOS: 000396521300010
WOS: 000396521300010
Anahtar Kelimeler
ONNO-type Schiff bases, cadmium, mercury, mononuclear complex, Hartree-Fock, density functional theory
Kaynak
Inorganic And Nano-Metal Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
47
Sayı
6
