A solvent-responsive coordination cage
dc.contributor.author | Kılbaş, Benan | |
dc.contributor.author | Mirtschin, Sebastian | |
dc.contributor.author | Scopelliti, Rosario | |
dc.contributor.author | Severin, Kay | |
dc.date.accessioned | 2020-04-30T22:38:53Z | |
dc.date.available | 2020-04-30T22:38:53Z | |
dc.date.issued | 2012 | |
dc.department | DÜ, Fen-Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.description | WOS: 000299949500005 | en_US |
dc.description.abstract | The solvent-induced structural rearrangement of synthetic supramolecular structures typically requires a pronounced change in solvent polarity. We describe a ruthenium-based coordination cage, whose geometry and topology can be altered dramatically by using two closely related solvents: chloroform and dichloromethane. In chloroform, we observe an octanuclear prismatic cage, whereas a tetranuclear complex is formed in dichloromethane. The basis of this unusual solvent-sensitivity is the incorporation of metallacrown recognition units into a flexible, kinetically labile nanostructure. | en_US |
dc.description.sponsorship | Swiss National Science FoundationSwiss National Science Foundation (SNSF); EPFL; TUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) | en_US |
dc.description.sponsorship | The work was supported by the Swiss National Science Foundation, by the EPFL and by the TUBITAK (Scientific and Technological Research Council of Turkey). | en_US |
dc.identifier.doi | 10.1039/c1sc00779c | en_US |
dc.identifier.endpage | 704 | en_US |
dc.identifier.issn | 2041-6520 | |
dc.identifier.issn | 2041-6539 | |
dc.identifier.issue | 3 | en_US |
dc.identifier.scopusquality | Q1 | en_US |
dc.identifier.startpage | 701 | en_US |
dc.identifier.uri | https://doi.org/10.1039/c1sc00779c | |
dc.identifier.uri | https://hdl.handle.net/20.500.12684/2498 | |
dc.identifier.volume | 3 | en_US |
dc.identifier.wos | WOS:000299949500005 | en_US |
dc.identifier.wosquality | Q1 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Royal Soc Chemistry | en_US |
dc.relation.ispartof | Chemical Science | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | A solvent-responsive coordination cage | en_US |
dc.type | Article | en_US |
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