A solvent-responsive coordination cage

dc.contributor.authorKılbaş, Benan
dc.contributor.authorMirtschin, Sebastian
dc.contributor.authorScopelliti, Rosario
dc.contributor.authorSeverin, Kay
dc.date.accessioned2020-04-30T22:38:53Z
dc.date.available2020-04-30T22:38:53Z
dc.date.issued2012
dc.departmentDÜ, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.descriptionWOS: 000299949500005en_US
dc.description.abstractThe solvent-induced structural rearrangement of synthetic supramolecular structures typically requires a pronounced change in solvent polarity. We describe a ruthenium-based coordination cage, whose geometry and topology can be altered dramatically by using two closely related solvents: chloroform and dichloromethane. In chloroform, we observe an octanuclear prismatic cage, whereas a tetranuclear complex is formed in dichloromethane. The basis of this unusual solvent-sensitivity is the incorporation of metallacrown recognition units into a flexible, kinetically labile nanostructure.en_US
dc.description.sponsorshipSwiss National Science FoundationSwiss National Science Foundation (SNSF); EPFL; TUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThe work was supported by the Swiss National Science Foundation, by the EPFL and by the TUBITAK (Scientific and Technological Research Council of Turkey).en_US
dc.identifier.doi10.1039/c1sc00779cen_US
dc.identifier.endpage704en_US
dc.identifier.issn2041-6520
dc.identifier.issn2041-6539
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage701en_US
dc.identifier.urihttps://doi.org/10.1039/c1sc00779c
dc.identifier.urihttps://hdl.handle.net/20.500.12684/2498
dc.identifier.volume3en_US
dc.identifier.wosWOS:000299949500005en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofChemical Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleA solvent-responsive coordination cageen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
2498.pdf
Boyut:
377.89 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text