The Potential of Tempo-Oxidized Cellulose Nanofibers to Replace Ethylene-Propylene-Diene Monomer Rubber

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dc.contributor.authorDikmen Küçük, Sibel
dc.contributor.authorTozluoglu, A.
dc.contributor.authorGuner, Y.
dc.date.accessioned2026-08-25T19:46:31Z
dc.date.available2026-08-25T19:46:31Z
dc.date.issued2020
dc.departmentRektörlük, Rektörlüğe Bağlı Birimler, Çevre ve Sağlık Teknolojilerinde İhtisaslaşma Koordinatörlüğü
dc.description.abstractIn recent years, petroleum-based polymers began to be limited due to effects on human and environmental point of view in many countries. Thus, organic-based biodegradable materials have attracted much interest in the composite industry because of environmental concerns. As a result of this, it has been asked that inorganic and petroleum-based materials should be reduced and altered with biodegradable materials. In this point, in this study, it is aimed to investigate the potential of use of TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl)-mediated oxidation nano-fibrillated cellulose instead of EPDM (ethylene-propylene-diene monomer) rubber, which is a petroleum-based material. Thus, the exchange of petroleum-based EPDM rubber with organic based cellulose nanofibers, which are environmentally friendly (green) and biodegradable, will be realized. The effect of tempo-oxidized cellulose nanofibers (TCNF) instead of EPDM rubber was analyzed by rheological, mechanical, chemical, thermal and aging analyses. The aged surfaces were visually scrutinized and surface morphological changes were examined via scanning electron microscopy (SEM). The results obtained showed that TEMPO oxidation nano-fibrillated cellulose can be used at an amount of 1.0 and 2.2 phr resulting the values stay within tolerance according to customer standard and without any chemical degradation, crack, colour change or staining.
dc.identifier.endpage97
dc.identifier.issue3
dc.identifier.startpage102
dc.identifier.urihttps://hdl.handle.net/20.500.12684/23764
dc.identifier.volume14
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherWorld Academy of Science, Engineering and Technology
dc.relation.ispartofInternational Journal of Energy and Environmental Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_Yazar_20260825
dc.subjectEPDM
dc.subjectcellulose
dc.subjectgreen materials
dc.subjectnanofibrillated cellulose
dc.subjectTCNF
dc.subjecttempo-oxidized nanofiber
dc.titleThe Potential of Tempo-Oxidized Cellulose Nanofibers to Replace Ethylene-Propylene-Diene Monomer Rubber
dc.typeArticle

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