Peripherally substituted soluble nickel phthalocyanines: Synthesis, characterization, aggregation behavior and antioxidant properties
Küçük Resim Yok
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
World Scientific Publishing Co.
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Tetra-zwitterionic-substituted nickel(II) phthalocyanine derivatives were newly synthesized starting from nonionic 2(3), 9(10), 16(17), 23(24)-tetrakis-[2-(N-((3-dimethylamino)propyl) carbamate)oxyethyl)phthalocyaninato nickel (II). The novel compounds have been characterized by a combination of UV-vis, FT-IR and mass spectroscopies and elemental analysis. The critical micelle concentrations of the prepared compounds were measured, and the antioxidant activities were analyzed with radical scavenging ability of 1, 1-diphenyl-2-picrylhydrazyl (DPPH) and with 2, 2'-azino-bis(3- ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS). The zwitterionic molecules showed aggregated spectra in the UV-vis region, and they might be good surfactant candidates for the detergent industry with their appropriate critical micelle concentration (CMC) properties in water. The compounds exhibited ABTS radical scavenging activity and thus they have antioxidant activity. © 2021 by World Scientific Publishing Co. Pte. Ltd.
Açıklama
Anahtar Kelimeler
ABTS, Antioxidant properties, Critical micelle concentration, Soluble phthalocyanines, Zwitterionic substituted phthalocyanines
Kaynak
Porphyrin Science By Women (In 3 Volumes)
