A newly synthesized ionic liquid as an effective corrosion inhibitor for carbon steel in HCl medium: A combined experimental and computational studies

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dc.contributor.authorOzturk, Serkan
dc.contributor.authorGerengi, Husnu
dc.contributor.authorSolomon, Moses M.
dc.contributor.authorGece, Gokhan
dc.contributor.authorYildirim, Ayhan
dc.contributor.authorYildiz, Mesut
dc.date.accessioned2021-12-01T18:50:41Z
dc.date.available2021-12-01T18:50:41Z
dc.date.issued2021
dc.department[Belirlenecek]en_US
dc.description.abstractSurfactants present exciting adsorption chemistry due to their dual nature, i.e the present of the hydrophobic and hydrophilic parts in their structures. However, the inhibition performance of surfactants is influenced by their chemical structure as well as the nature of the electrolyte. In acidic media, high concentration of tri-cationic surfactants is required for effective surface protection. Herein, we report the synthesis of a novel tri-cationic surfactant containing three quaternized nitrogen atoms and its corrosion inhibitive effect for carbon steel in 1 M aqueous HCl medium. The molecular structure of the surfactant was elucidated by 1H NMR and C-13 NMR spectroscopic techniques and its anti-corrosion activity was investigated by electrochemical impedance spectroscopy, potentiodynamic polarization and dynamic electrochemical impedance spectroscopy methods. The results obtained from the corrosion studies show that the synthesized surfactant is quite effective against the low carbon steel corrosion and at low inhibitor concentration. The inhibition efficiency obtained at 5 mg/L concentration is above 90%, showing that the anti-corrosion effect of the synthesized surfactant on the metal surface is strong even at low inhibitor concentration. Moreover, some physicochemical parameters namely, the critical micelle concentration, surface tension, micelle formation free energy, and emulsion stability have been calculated and used to explain the correlation with the corrosion inhibition mechanism. Additionally, to support the results from the electrochemical measurements, surface morphological examination using energy dispersive Xray spectroscopy (EDAX) and scanning electron microscope (SEM) methods have been performed. The EDAX and SEM results prove the adsorption of the tri-cationic surfactant molecule on the metal surface. The adsorption followed the Langmuir adsorption isotherm and calculated Kads (equilibrium constant of the adsorption process) value reflects strong interaction. More so, density functional theory (DFT) results corroborate the experimental results. The synthesized tri-cationic surfactant is a potential candidate for the formulation of acid corrosion inhibitor for acid cleaning applications.en_US
dc.description.sponsorshipResearch Foundation of Bursa Uludag University [OUAP(F)-2019/15]en_US
dc.description.sponsorshipThis work was supported by the Research Foundation of Bursa Uludag University under the Project Number: OUAP(F)-2019/15.en_US
dc.identifier.doi10.1016/j.mtcomm.2021.102905
dc.identifier.issn2352-4928
dc.identifier.urihttps://doi.org/10.1016/j.mtcomm.2021.102905
dc.identifier.urihttps://hdl.handle.net/20.500.12684/10911
dc.identifier.volume29en_US
dc.identifier.wosWOS:000712117200006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofMaterials Today Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectsynthesisen_US
dc.subjecttri-cationic surfactanten_US
dc.subjectCorrosion inhibitionen_US
dc.subjectphysicochemical propertiesen_US
dc.subjectCationic Gemini Surfactantsen_US
dc.subjectMild-Steelen_US
dc.subjectSt37 Steelen_US
dc.subjectAcidic-Solutionen_US
dc.subjectHalide-Ionsen_US
dc.subjectNanoparticles Compositeen_US
dc.subjectSynergistic Inhibitionen_US
dc.subjectDicationic Surfactantsen_US
dc.subjectH2So4 Solutionen_US
dc.subjectSchiff-Basesen_US
dc.titleA newly synthesized ionic liquid as an effective corrosion inhibitor for carbon steel in HCl medium: A combined experimental and computational studiesen_US
dc.typeArticleen_US

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