Orhan, ErsinGarci, AmineTherrien, Bruno2020-05-012020-05-0120150020-16931873-3255https://doi.org/10.1016/j.ica.2015.09.002https://hdl.handle.net/20.500.12684/5983orhan, ersin/0000-0002-5461-1005; Therrien, Bruno/0000-0002-0388-2745WOS: 000363867500002Cationic arene ruthenium metalla-prisms of the general formula [Ru-6(p-cymene)(6)(tpmtt)(2)(OO boolean AND OO)(3)](6+) (tpmtt = 1,3,5-tris(pyridin-4-ylmethyl)-1,3,5-triazinane-2,4,6-trione) have been obtained from the corresponding dinuclear arene ruthenium complexes [Ru-2(p-cymene)(2)(OO boolean AND OO)Cl-2] (OO boolean AND OO = oxalato (ox), 2,5-dioxido-1,4-benzoquinonato (dobq), 2,5-dichloro-1,4-benzoquinonato (dClbq), 2,5-dioxido-3-undecyl-1,4-benzoquinonato (dubq), 5,8-dioxido-1,4-naphtoquinonato (donq)) by reaction with the tridentate tpmtt ligand and silver trifluoromethanesulfonate. These cationic arene ruthenium metalla-prisms have been isolated and characterized as their triflate salts. Upon formation of the metalla-prisms, the two tpmtt panels are in close proximity and do not allow encapsulation of guest molecules. (C) 2015 Elsevier B.V. All rights reserved.en10.1016/j.ica.2015.09.002info:eu-repo/semantics/closedAccessArene ligandRutheniumMetalla-assembliesSupramolecular chemistryHalf-sandwich complexesArticle43859WOS:000363867500002Q2Q2