Allı, AbdulkadirAllı, SemaBecer, C. RemziHazer, Baki2020-04-302020-04-3020140003-021X1558-9331https://doi.org/10.1007/s11746-014-2418-1https://hdl.handle.net/20.500.12684/3959Becer, C. Remzi/0000-0003-0968-6662;WOS: 000335153500016One-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.en10.1007/s11746-014-2418-1info:eu-repo/semantics/closedAccessAutoxidationOne-pot polymerizationepsilon-CaprolactonePolymeric linoleic acid peroxidesArticle915849858WOS:000335153500016Q2Q2